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Chloromethane, also called methyl chloride, Refrigerant-40, R-40 or HCC 40, is an organic compound with the chemical formula CH 3 Cl. One of the haloalkanes , it is a colorless, sweet-smelling, flammable gas.
Phase behavior Triple point: 175.43 K (–97.72 °C), 870 Pa Critical point: 416 K (143 °C), 6714.4 kPa Std enthalpy change of fusion, Δ fus H o: 6.43 kJ/mol
For example, the industrial production of chloroethane proceeds by the reaction of ethylene with HCl: [citation needed] H 2 C=CH 2 + HCl → CH 3 CH 2 Cl. In oxychlorination, hydrogen chloride instead of the more expensive chlorine is used for the same purpose: CH 2 =CH 2 + 2 HCl + 1 ⁄ 2 O 2 → ClCH 2 CH 2 Cl + H 2 O.
DCM is produced by treating either chloromethane or methane with chlorine gas at 400–500 °C. At these temperatures, both methane and chloromethane undergo a series of reactions producing progressively more chlorinated products. In this way, an estimated 400,000 tons were produced in the US, Europe, and Japan in 1993. [12] CH 4 + Cl 2 → CH ...
However, its production remains high, as it is a key precursor of PTFE. [ 41 ] Although chloroform has properties such as a low boiling point, and a low global warming potential of only 31 (compared to the 1760 of R-22), which are appealing properties for a refrigerant, there is little information to suggest that it has seen widespread use as a ...
An example of photochlorination at low temperatures and under ambient pressure is the chlorination of chloromethane to dichloromethane. The liquefied chloromethane (boiling point -24 °C) is mixed with chlorine in the dark and then irradiated with a mercury-vapor lamp. The resulting dichloromethane has a boiling point of 41 °C and is later ...
The relative rates at which different halogens react vary considerably: [citation needed] fluorine (108) > chlorine (1) > bromine (7 × 10 −11) > iodine (2 × 10 −22).. Radical fluorination with the pure element is difficult to control and highly exothermic; care must be taken to prevent an explosion or a runaway reaction.
Hence, it is inferred that hydride transfer is not rate-determining. Significant competitive isotope effect with C 2 H 2 D 2, ( k H / k D = ~1.9), suggests that rate determining step be prior to formation of acetaldehyde. High concentrations of chloride and copper(II) chloride favor formation of a new product, chlorohydrin.