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Triphenyl phosphate (TPhP) is the chemical compound with the formula OP(OC 6 H 5) 3. It is the simplest aromatic organophosphate. This colourless solid is the ester (triester) of phosphoric acid and phenol. It is used as a plasticizer and a fire retardant in a wide variety of settings and products. [3]
Triphenylphosphine oxide (often abbreviated TPPO) is the organophosphorus compound with the formula OP(C 6 H 5) 3, also written as Ph 3 PO or PPh 3 O (Ph = C 6 H 5).It is one of the more common phosphine oxides.
The phosphorus-containing product is triphenylphosphine sulfide, Ph 3 PS. This reaction can be employed to assay the "labile" S 0 content of a sample, say vulcanized rubber. Triphenylphosphine selenide, Ph 3 PSe, may be easily prepared via treatment of PPh 3 with red (alpha-monoclinic) Se. Salts of selenocyanate, SeCN −, are used as the Se 0 ...
Triphenyl phosphite ozonide (TPPO) is a chemical compound with the formula PO 3 (C 6 H 5 O) 3 that is used to generate singlet oxygen. [ 1 ] [ 2 ] When TPPO is mixed with amines , the ozonide breaks down into singlet oxygen and leaves behind triphenyl phosphite . [ 2 ]
Phosphites are oxidized to phosphate esters: P(OR) 3 + [O] → OP(OR) 3. This reaction underpins the commercial use of some phosphite esters as stabilizers in polymers. [6] Alkyl phosphite esters are used in the Perkow reaction for the formation of vinyl phosphonates, and in the Michaelis–Arbuzov reaction to form phosphonates.
Triphenylphosphine dichloride, (C 6 H 5) 3 PCl 2, is a chlorinating agent widely used in organic chemistry. Applications include the conversion of alcohols and ethers to alkyl chlorides, the cleavage of epoxides to vicinal dichlorides and the chlorination of carboxylic acids to acyl chlorides. [2]
Triphenylphosphite is a precursor to trimethylphosphine, it serves as a source of P 3+ that is less electrophilic than phosphorus trichloride: [1] (C 6 H 5 O) 3 P + 3 CH 3 MgBr → P(CH 3) 3 + 3 "MgBrOC 6 H 5 " Triphenylphosphite is quaternized by methyl iodide: [2] (C 6 H 5 O) 3 P + CH 3 I → [CH 3 (C 6 H 5 O) 3 P] + I −
Triphenylphosphine sulfide (IUPAC name: triphenyl-λ 5-phosphanethione) is the organophosphorus compound with the formula (C 6 H 5) 3 PS, usually written Ph 3 PS (where Ph = phenyl). It is a colourless solid, which is soluble in a variety of organic solvents.