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The van Deemter equation is a hyperbolic function that predicts that there is an optimum velocity at which there will be the minimum variance per unit column length and, thence, a maximum efficiency. The van Deemter equation was the result of the first application of rate theory to the chromatography elution process.
Gas chromatography (GC) is a common type of chromatography used in analytical chemistry for separating and analyzing compounds that can be vaporized without decomposition. Typical uses of GC include testing the purity of a particular substance, or separating the different components of a mixture. [1]
In unit systems where force is a derived unit, like in SI units, g c is equal to 1. In unit systems where force is a primary unit, like in imperial and US customary measurement systems , g c may or may not equal 1 depending on the units used, and value other than 1 may be required to obtain correct results. [ 2 ]
The components of the sample move through the column, each at a different velocity, which are a function of specific physical interactions with the adsorbent, the stationary phase. The velocity of each component depends on its chemical nature, on the nature of the stationary phase (inside the column) and on the composition of the mobile phase.
Spatial acceleration entails looking at a fixed (unmoving) point in space and observing the change in velocity of the particles that pass through that point. This is similar to the definition of acceleration in fluid dynamics, where typically one measures velocity and/or acceleration at a fixed point inside a testing apparatus.
Let the forces on the system be F j (j = 1, 2, …, m) be applied to points with Cartesian coordinates r j (j = 1, 2, …, m), then the virtual work generated by a virtual displacement from the equilibrium position is given by = =.
A twist is a screw used to represent the velocity of a rigid body as an angular velocity around an axis and a linear velocity along this axis. All points in the body have the same component of the velocity along the axis, however the greater the distance from the axis the greater the velocity in the plane perpendicular to this axis.
Linear motion, also called rectilinear motion, [1] is one-dimensional motion along a straight line, and can therefore be described mathematically using only one spatial dimension. The linear motion can be of two types: uniform linear motion , with constant velocity (zero acceleration ); and non-uniform linear motion , with variable velocity ...