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Enthalpy change of solution in water at 25 °C for some selected compounds [2] Compound ΔH o in kJ/mol; hydrochloric acid: −74.84 ammonium nitrate +25.69 ammonia: −30.50 potassium hydroxide: −57.61 caesium hydroxide: −71.55 sodium chloride +3.87 potassium chlorate +41.38 acetic acid: −1.51 sodium hydroxide: −44.50
In thermochemistry, the heat of dilution, or enthalpy of dilution, refers to the enthalpy change associated with the dilution process of a component in a solution at a constant pressure. If the initial state of the component is a pure liquid (presuming the solution is liquid), the dilution process is equal to its dissolution process and the ...
In aqueous solution, ammonia deprotonates a small fraction of the water to give ammonium and hydroxide according to the following equilibrium: . NH 3 + H 2 O ⇌ NH + 4 + OH −.. In a 1 M ammonia solution, about 0.42% of the ammonia is converted to ammonium, equivalent to pH = 11.63 because [NH +
Nitric acid, with a pK value of around −1.7, behaves as a strong acid in aqueous solutions with a pH greater than 1. [23] At lower pH values it behaves as a weak acid. pK a values for strong acids have been estimated by theoretical means. [24] For example, the pK a value of aqueous HCl has been estimated as −9.3.
Ammonium chloride is an inorganic chemical compound with the chemical formula N H 4 Cl, also written as [NH 4]Cl.It is an ammonium salt of hydrogen chloride.It consists of ammonium cations [NH 4] + and chloride anions Cl −.
For many substances, the formation reaction may be considered as the sum of a number of simpler reactions, either real or fictitious. The enthalpy of reaction can then be analyzed by applying Hess' law, which states that the sum of the enthalpy changes for a number of individual reaction steps equals the enthalpy change of the overall reaction.
Standard enthalpy of neutralization is the change in enthalpy that occurs when an acid and base undergo a neutralization reaction to form one mole of water. For example in aqueous solution , the standard enthalpy of neutralization of hydrochloric acid and the base magnesium hydroxide refers to the reaction HCl (aq) + 1/2 Mg(OH) 2 → 1/2 MgCl 2 ...
The Van 't Hoff equation relates the change in the equilibrium constant, K eq, of a chemical reaction to the change in temperature, T, given the standard enthalpy change, Δ r H ⊖, for the process. The subscript r {\displaystyle r} means "reaction" and the superscript ⊖ {\displaystyle \ominus } means "standard".