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The degree of dissociation in gases is denoted by the symbol α, where α refers to the percentage of gas molecules which dissociate. Various relationships between K p and α exist depending on the stoichiometry of the equation. The example of dinitrogen tetroxide (N 2 O 4) dissociating to nitrogen dioxide (NO 2) will be taken.
Enthalpy change of solution in water at 25 °C for some selected compounds [2] Compound ΔH o in kJ/mol; hydrochloric acid: −74.84 ammonium nitrate +25.69 ammonia: −30.50 potassium hydroxide: −57.61 caesium hydroxide: −71.55 sodium chloride +3.87 potassium chlorate +41.38 acetic acid: −1.51 sodium hydroxide: −44.50
Copper(II) sulfate is an inorganic compound with the chemical formula Cu SO 4.It forms hydrates CuSO 4 ·nH 2 O, where n can range from 1 to 7. The pentahydrate (n = 5), a bright blue crystal, is the most commonly encountered hydrate of copper(II) sulfate, [10] while its anhydrous form is white. [11]
The assumption that solution properties are independent of nature of solute particles is exact only for ideal solutions, which are solutions that exhibit thermodynamic properties analogous to those of an ideal gas, and is approximate for dilute real solutions. In other words, colligative properties are a set of solution properties that can be ...
The dissociation involves cleaving of the molecular bonds in the adsorbate, and formation of new bonds with the substrate. Breaking the atomic bonds of the dissociating molecule requires a large amount of energy, thus dissociative adsorption is an example of chemisorption , where strong adsorbate-substrate bonds are created. [ 1 ]
If this convention is used, then the values are in the same range as monovalent ions, e.g. 59.5 S cm 2 mol −1 for 1 / 2 Ca 2+ and 80.0 S cm 2 mol −1 for 1 / 2 SO 2− 4. [4] From the ionic molar conductivities of cations and anions, effective ionic radii can be calculated using the concept of Stokes radius.
Dissociative recombination is a chemical process in which a positive polyatomic ion recombines with an electron, and as a result, the neutral molecule dissociates. [1] This reaction is important for interstellar and atmospheric chemistry.
When solute particles neither dissociate nor associate in solution, i equals 1 (e.g. glucose in water). The value of i is the actual number of particles in solution after dissociation divided by the number of formula units initially dissolved in solution and means the number of particles per formula unit of the solute when a solution is dilute.