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MEKP is a colorless oily liquid. It is widely used in vulcanization (crosslinking) of polymers. [3] It is derived from the reaction of methyl ethyl ketone and hydrogen peroxide under acidic conditions. Several products result from this reaction including a cyclic dimer. [4] The linear dimer, the topic of this article, is the most prevalent.
Vinyl ester resin is extensively used to manufacture FRP tanks and vessels as per BS4994. For laminating process, vinyl ester is usually initiated with methyl ethyl ketone peroxide. It has greater strength and mechanical properties than polyester and less than epoxy resin. Renewable precursors to vinyl ester resins have been developed. [2]
Thus, organic peroxides are useful as initiators for some types of polymerization, such as the acrylic, unsaturated polyester, and vinyl ester resins used in glass-reinforced plastics. MEKP and benzoyl peroxide are commonly used for this purpose. However, the same property also means that organic peroxides can explosively combust.
Since vinyl ester resins must be pre-accelerated with amine accelerator or cobalt, their processing time at room temperature is shorter than with epoxy-based prepregs. Catalysts (also called hardeners) include peroxides such as methyl ethyl ketone peroxide (MEKP), acetyl acetone peroxide (AAP) or cyclohexanone peroxide (CHP).
The most common resin system used for the spray-up process is general purpose or DCDP polyester; isophthalic polyesters and vinyl ester resins are also sometimes used. Fast-reacting resins with a pot life of 30 to 40 minutes are typical. The resin often contains a significant amount of filler.
Vinyl ester resin is an example of a synthetic resin. [1] Synthetic resins are industrially produced resins, typically viscous substances that convert into rigid polymers by the process of curing. In order to undergo curing, resins typically contain reactive end groups, [2] such as acrylates or epoxides.
These are made by the reaction of phenols, formaldehyde and primary amines which at elevated temperatures (400 °F (200 °C)) undergo ring–opening polymerisation forming polybenzoxazine thermoset networks; when hybridised with epoxy and phenolic resins the resulting ternary systems have glass transition temperatures in excess of 490 °F (250 °C).
Vinyl resin may refer to: ... Vinyl ester resin, also known as just "vinyl ester" This page was last edited on 25 April 2020, at 16:49 (UTC). Text is available ...