Search results
Results From The WOW.Com Content Network
An incomplete valence shell electron configuration, due to the noble gas configuration of the cation producing better shielding and less polarizing power, for example Hg 2+ (r+ = 102 pm) is more polarizing than Ca 2+ (r+ = 100 pm) The "size" of the charge in an ionic bond depends on the number of electrons transferred.
Thus, anions (negatively charged ions) are larger than the parent molecule or atom, as the excess electron(s) repel each other and add to the physical size of the ion, because its size is determined by its electron cloud. Cations are smaller than the corresponding parent atom or molecule due to the smaller size of the electron cloud.
Ionic bonding can result from a redox reaction when atoms of an element (usually metal), whose ionization energy is low, give some of their electrons to achieve a stable electron configuration. In doing so, cations are formed. An atom of another element (usually nonmetal) with greater electron affinity accepts one or more electrons to attain a ...
The even electron rule states that ions with an even number of electrons (cations but not radical ions) tend to form even-electron fragment ions and odd-electron ions (radical ions) form odd-electron ions or even-electron ions. [9] Even-electron species tend to fragment to another even-electron cation and a neutral molecule rather than two odd ...
The hydrogen anion, with its loosely held two-electron cloud, has a larger radius than the neutral atom, which in turn is much larger than the bare proton of the cation. Hydrogen forms the only cation that has no electrons, but even cations that (unlike hydrogen) still retain one or more electrons are still smaller than the neutral atoms or ...
[17] [18] The familiar alkynes have a carbon-carbon triple bond (bond order 3) and a linear geometry of 180° bond angles (figure A in reference [19]). However, further down in the group ( silicon , germanium , and tin ), formal triple bonds have an effective bond order 2 with one lone pair (figure B [ 19 ] ) and trans -bent geometries.
In the simple aromatic ring of benzene, the delocalization of six π electrons over the C 6 ring is often graphically indicated by a circle. The fact that the six C-C bonds are equidistant is one indication that the electrons are delocalized; if the structure were to have isolated double bonds alternating with discrete single bonds, the bond would likewise have alternating longer and shorter ...
When an atom loses an electron to form a cation, the other electrons are more attracted to the nucleus, and the radius of the ion gets smaller. Similarly, when an electron is added to an atom, forming an anion, the added electron increases the size of the electron cloud by interelectronic repulsion.