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Static measurements yield values in-between the advancing and receding contact angle depending on deposition parameters (e.g. velocity, angle, and drop size) and drop history (e.g. evaporation from time of deposition). Contact angle hysteresis is defined as θ A – θ R although the term is also used to describe the expression cos θ R – cos ...
Contact angles greater than 90° (high contact angle) generally mean that wetting of the surface is unfavorable, so the fluid will minimize contact with the surface and form a compact liquid droplet. For water, a wettable surface may also be termed hydrophilic and a nonwettable surface hydrophobic. Superhydrophobic surfaces have contact angles ...
As with the tilt method, the difference between the advancing and receding contact angles is the contact angle hysteresis. Most researchers prefer the tilt method; the add/remove method requires that a tip or needle stay embedded in the drop which can affect the accuracy of the values, especially the receding contact angle.
An ideal solid surface is flat, rigid, perfectly smooth, and chemically homogeneous, and has zero contact angle hysteresis. Zero hysteresis implies the advancing and receding contact angles are equal. Figure 1: Contact angle for a liquid droplet on a solid surface. In other words, only one thermodynamically stable contact angle exists. When a ...
Contact angle is a measure of static hydrophobicity, and contact angle hysteresis and slide angle are dynamic measures. Contact angle hysteresis is a phenomenon that characterizes surface heterogeneity. [15] When a pipette injects a liquid onto a solid, the liquid will form some contact angle.
The simplest way of measuring the contact angle of a sessile drop is with a contact angle goniometer, which allows the user to measure the contact angle visually. A droplet is deposited by a syringe which is positioned above the sample surface, and a high resolution camera captures the image from the profile or side view.
The captive bubble method is a method for measuring the contact angle between a liquid and a solid, by using drop shape analysis. [1] In this method, a bubble of air is injected beneath a solid, the surface of which is located in the liquid, instead of placing a drop on the solid as in the case of the sessile drop technique.
If complete wetting is assumed (contact angle = 0), no correction factors are required to calculate surface tensions when using the Wilhelmy plate, unlike for a du Noüy ring. In addition, because the plate is not moved during measurements, the Wilhelmy plate allows accurate determination of surface kinetics on a wide range of timescales, and ...