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1-Bromo-3-chloro-5,5-dimethylhydantoin (BCDMH or bromochlorodimethylhydantoin) is a chemical structurally related to hydantoin.It is a white crystalline compound with a slight bromine and acetone odor and is insoluble in water, but soluble in acetone.
A traditional method for the manufacture of KBr is the reaction of potassium carbonate with an iron(III, II) bromide, Fe 3 Br 8, made by treating scrap iron under water with excess bromine: [4] 4 K 2 CO 3 + Fe 3 Br 8 8 KBr + Fe 3 O 4 + 4 CO 2 {\displaystyle {\ce {4 K2CO3 + Fe3Br8 -> 8 KBr + Fe3O4 + 4 CO2}}}
Industrially, it is mainly produced by the reaction of hydrogen gas with bromine gas at 200–400 °C with a platinum catalyst. However, reduction of bromine with red phosphorus is a more practical way to produce hydrogen bromide in the laboratory: [2] 2 P + 6 H 2 O + 3 Br 2 → 6 HBr + 2 H 3 PO 3 H 3 PO 3 + H 2 O + Br 2 → 2 HBr + H 3 PO 4
Bond energies to bromine tend to be lower than those to chlorine but higher than those to iodine, and bromine is a weaker oxidising agent than chlorine but a stronger one than iodine. This can be seen from the standard electrode potentials of the X 2 /X − couples (F, +2.866 V; Cl, +1.395 V; Br, +1.087 V; I, +0.615 V; At, approximately +0.3 V).
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Bromine (35 Br) has two stable isotopes, 79 Br and 81 Br, and 35 known radioisotopes, the most stable of which is 77 Br, with a half-life of 57.036 hours.. Like the radioactive isotopes of iodine, radioisotopes of bromine, collectively radiobromine, can be used to label biomolecules for nuclear medicine; for example, the positron emitters 75 Br and 76 Br can be used for positron emission ...
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