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This is especially important for solid samples where there is a strong matrix influence. [5] In cases with complex or unknown matrices, the standard addition method can be used. [ 3 ] In this technique, the response of the sample is measured and recorded, for example, using an electrode selective for the analyte.
This method, however, assumes the pure aqueous solution of silver and a photographic waste sample have the same matrix and therefore the waste samples are free of matrix effect. Spreadsheet for standard addition example on determining the silver concentration of photographic film waste.
Free-flow electrophoresis (FFE), also known as carrier-free electrophoresis, is a matrix-free, high-voltage electrophoretic separation technique. FFE is an analogous technique to capillary electrophoresis, with a comparable resolution, that can be used for scientific questions, where semi-preparative and preparative amounts of samples are needed.
Synonym for binary matrix or logical matrix. Alternant matrix: A matrix in which successive columns have a particular function applied to their entries. Alternating sign matrix: A square matrix with entries 0, 1 and −1 such that the sum of each row and column is 1 and the nonzero entries in each row and column alternate in sign. Anti-diagonal ...
Simple cases, where observations are complete, can be dealt with by using the sample covariance matrix. The sample covariance matrix (SCM) is an unbiased and efficient estimator of the covariance matrix if the space of covariance matrices is viewed as an extrinsic convex cone in R p×p; however, measured using the intrinsic geometry of positive ...
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For example, if A is a 3-by-0 matrix and B is a 0-by-3 matrix, then AB is the 3-by-3 zero matrix corresponding to the null map from a 3-dimensional space V to itself, while BA is a 0-by-0 matrix. There is no common notation for empty matrices, but most computer algebra systems allow creating and computing with them.
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