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In organic chemistry, regioselectivity is the preference of chemical bonding or breaking in one direction over all other possible directions. [1] [2] It can often apply to which of many possible positions a reagent will affect, such as which proton a strong base will abstract from an organic molecule, or where on a substituted benzene ring a further substituent will be added.
Enantioselective synthesis, also called asymmetric synthesis, [1] is a form of chemical synthesis.It is defined by IUPAC as "a chemical reaction (or reaction sequence) in which one or more new elements of chirality are formed in a substrate molecule and which produces the stereoisomeric (enantiomeric or diastereomeric) products in unequal amounts."
The Psychopathology of Everyday Life. Everyday life is a key concept in cultural studies and is a specialized subject in the field of sociology.Some argue that, motivated by capitalism and industrialism's degrading effects on human existence and perception, writers and artists of the 19th century turned more towards self-reflection and the portrayal of everyday life represented in their ...
Ahead, we’ve rounded up 50 holy grail hyperbole examples — some are as sweet as sugar, and some will make you laugh out loud. 50 common hyperbole examples I’m so hungry, I could eat a horse.
By 1991, Newsweek reported that the schools at Reggio Emilia were among the top school systems in the world. [ 1 ] On May 24, 1994, the nonprofit organization Friends of Reggio Children International Association was founded to promote the work of Loris Malaguzzi and to organize professional development and cultural events around the approach. [ 7 ]
A famous example is the Luche Reduction, where an oxophilic metal makes the carbonyl of a conjugated ketone more reactive and directs the reducing agent. [6] On the other hand, copper organometallics have high affinity with carbon-carbon multiple bonds and are used for conjugate addition of nucleophiles into a conjugated ketone.
Selectivity also provides some immunity to blanketing interference. LC circuits are often used as filters; the Q ("Quality" factor) determines the bandwidth of each LC tuned circuit in the radio. The L/C ratio, in turn, determines their Q and so their selectivity, because the rest of the circuit - the aerial or amplifier feeding the tuned ...
The conditions for Stille's experiments differ significantly from industrial process conditions. Other studies using normal industrial Wacker conditions (except with high chloride and high copper chloride concentrations) also yielded products that inferred nucleophilic attack was an anti-addition reaction. [15]