Search results
Results From The WOW.Com Content Network
Enthalpies of melting and boiling for pure elements versus temperatures of transition, demonstrating Trouton's rule. In thermodynamics, the enthalpy of fusion of a substance, also known as (latent) heat of fusion, is the change in its enthalpy resulting from providing energy, typically heat, to a specific quantity of the substance to change its state from a solid to a liquid, at constant pressure.
In some texts, the heats of phase transitions are called latent heats (for example, latent heat of fusion). Molar enthalpy of zinc above 298.15 K and at 1 atm pressure, showing discontinuities at the melting and boiling points. The ΔH°m of zinc is 7323 J/mol, and the ΔH°v is 115 330 J/mol.
Latent heat is energy released or absorbed by a body or a thermodynamic system during a constant-temperature process. Two common forms of latent heat are latent heat of fusion and latent heat of vaporization . These names describe the direction of energy flow when changing from one phase to the next: from solid to liquid, and liquid to gas.
J.A. Dean (ed), Lange's Handbook of Chemistry (15th Edition), McGraw-Hill, 1999; Section 6, Thermodynamic Properties; Table 6.4, Heats of Fusion, Vaporization, and Sublimation and Specific Heat at Various Temperatures of the Elements and Inorganic Compounds
The amount of energy required for a phase change is known as latent heat. The "cooling rate" is the slope of the cooling curve at any point. Alloys have a melting point range. It solidifies as shown in the figure above. First, the molten alloy reaches to liquidus temperature and then freezing range starts.
Enthalpies of melting and boiling for pure elements versus temperatures of transition, demonstrating Trouton's rule. In thermodynamics, Trouton's rule states that the (molar) entropy of vaporization is almost the same value, about 85–88 J/(K·mol), for various kinds of liquids at their boiling points. [1]
High latent heat of fusion per unit volume; High specific heat, high density, and high thermal conductivity; Small volume changes on phase transformation and small vapor pressure at operating temperatures to reduce the containment problem; Congruent melting; Kinetic properties High nucleation rate to avoid supercooling of the liquid phase
Additionally, the solution of the Cahn–Hilliard equation for a binary mixture is reasonably comparable with the solution of a Stefan problem. [11] In this comparison, the Stefan problem was solved using a front-tracking, moving-mesh method with homogeneous Neumann boundary conditions at the outer boundary. Also, Stefan problems can be applied ...