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The osmotic pressure is proportional to the concentration of solute particles ci and is therefore a colligative property. As with the other colligative properties, this equation is a consequence of the equality of solvent chemical potentials of the two phases in equilibrium.
The proportionality to concentration means that osmotic pressure is a colligative property. Note the similarity of this formula to the ideal gas law in the form P = n V R T = c gas R T {\textstyle P={\frac {n}{V}}RT=c_{\text{gas}}RT} where n is the total number of moles of gas molecules in the volume V , and n / V is the molar concentration of ...
Osmotic pressure is a colligative property, meaning that the property depends on the concentration of the solute, but not on its content or chemical identity. Osmotic gradient The osmotic gradient is the difference in concentration between two solutions on either side of a semipermeable membrane , and is used to tell the difference in ...
Osmotic concentration, formerly known as osmolarity, [1] is the measure of solute concentration, defined as the number of osmoles (Osm) of solute per litre (L) of solution (osmol/L or Osm/L). The osmolarity of a solution is usually expressed as Osm/L (pronounced "osmolar"), in the same way that the molarity of a solution is expressed as "M ...
For liquid solutions, the osmotic coefficient is often used to calculate the salt activity coefficient from the solvent activity, or vice versa. For example, freezing point depression measurements, or measurements of deviations from ideality for other colligative properties, allows calculation of the salt activity coefficient through the osmotic coefficient.
The van 't Hoff factor i (named after Dutch chemist Jacobus Henricus van 't Hoff) is a measure of the effect of a solute on colligative properties such as osmotic pressure, relative lowering in vapor pressure, boiling-point elevation and freezing-point depression.
colligative property Any property of a solution that depends upon the ratio of the number of solute particles to the number of solvent particles in the solution, and not on the nature of the chemical species present. Examples include osmotic pressure, freezing-point depression, and boiling-point elevation. colloid
b c is the colligative molality, calculated by taking dissociation into account since the boiling point elevation is a colligative property, dependent on the number of particles in solution. This is most easily done by using the van 't Hoff factor i as b c = b solute · i , where b solute is the molality of the solution. [ 3 ]