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The freezing point is the temperature at which the liquid solvent and solid solvent are at equilibrium, so that their vapor pressures are equal. When a non-volatile solute is added to a volatile liquid solvent, the solution vapour pressure will be lower than that of the pure solvent.
The atmospheric pressure boiling point of a liquid (also known as the normal boiling point) is the temperature at which the vapor pressure equals the ambient atmospheric pressure. With any incremental increase in that temperature, the vapor pressure becomes sufficient to overcome atmospheric pressure and cause the liquid to form vapor bubbles.
The boiling point of water is the temperature at which the saturated vapor pressure equals the ambient pressure. Water supercooled below its normal freezing point has a higher vapor pressure than that of ice at the same temperature and is, thus, unstable. Calculations of the (saturation) vapor pressure of water are commonly used in meteorology.
At the lower freezing point, the vapor pressure of the liquid is equal to the vapor pressure of the corresponding solid, and the chemical potentials of the two phases are equal as well. The equality of chemical potentials permits the evaluation of the cryoscopic constant as K f = R M T f 2 / Δ f u s H {\displaystyle K_{f}=RMT_{f}^{2}/\Delta ...
log e of Glycerol vapor pressure. ... Freezing Points of Glycerine-Water Solutions Dow Chemical [6] or Freezing Points of Glycerol and Its Aqueous Solutions. [7]
Triple point: 150 K (−123 °C), 0.00043 Pa ... Log 10 of ethanol vapor pressure vs. temperature. ... Freezing temperature, °C 10 °C 20 °C
Temperature dependence of ethylene glycol vapor pressure. ... See also "Typical Freezing and Boiling Points of Aqueous Solutions of DOWTHERM SR-1 and DOWTHERM ...
A log-lin vapor pressure chart for various liquids. The higher the vapor pressure of a liquid at a given temperature, the lower the normal boiling point (i.e., the boiling point at atmospheric pressure) of the liquid. The vapor pressure chart to the right has graphs of the vapor pressures versus temperatures for a variety of liquids. [10]