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Xenon difluoride is a powerful fluorinating agent with the chemical formula XeF 2, and one of the most stable xenon compounds. Like most covalent inorganic fluorides it is moisture-sensitive. It decomposes on contact with water vapor, but is otherwise stable in storage. Xenon difluoride is a dense, colourless crystalline solid.
In addition to compounds where xenon forms a chemical bond, xenon can form clathrates—substances where xenon atoms or pairs are trapped by the crystalline lattice of another compound. One example is xenon hydrate (Xe· 5 + 3 ⁄ 4 H 2 O), where xenon atoms occupy vacancies in a lattice of water molecules. [32]
This bonding scheme is succinctly summarized by the following two resonance structures: I—I···I − ↔ I − ···I—I (where "—" represents a single bond and "···" represents a "dummy bond" with formal bond order 0 whose purpose is only to indicate connectivity), which when averaged reproduces the I—I bond order of 0.5 obtained ...
Organoxenon chemistry is the study of the properties of organoxenon compounds, which contain carbon to xenon chemical bonds. The first organoxenon compounds were divalent, such as (C 6 F 5) 2 Xe. The first tetravalent organoxenon compound, [C 6 F 5 XeF 2][BF 4], was synthesized in 2004. [1] So far, more than one hundred organoxenon compounds ...
Xenon tetrafluoride is a chemical compound with chemical formula XeF 4. It was the first discovered binary compound of a noble gas. [3] It is produced by the chemical reaction of xenon with fluorine: [4] [5] Xe + 2 F 2 → XeF 4. This reaction is exothermic, releasing an energy of 251 kJ/mol. [3]
In chemistry, bond order is a formal measure of the multiplicity of a covalent bond between two atoms. As introduced by Gerhard Herzberg, [1] building off of work by R. S. Mulliken and Friedrich Hund, bond order is defined as the difference between the numbers of electron pairs in bonding and antibonding molecular orbitals.
Xenon oxydifluoride is an inorganic compound with the molecular formula XeOF 2.The first definitive isolation of the compound was published on 3 March 2007, producing it by the previously-examined route of partial hydrolysis of xenon tetrafluoride.
These compounds have found use in the study of the structure and reactivity of fullerenes by means of the nuclear magnetic resonance of the noble gas atom. [65] Bonding in XeF 2 according to the 3-center-4-electron bond model. Noble gas compounds such as xenon difluoride (XeF 2) are considered to be hypervalent because they violate the octet rule.