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Atomic absorption spectroscopy (AAS) is a spectroanalytical procedure for the quantitative measurement of chemical elements. AAS is based on the absorption of light by free metallic ions that have been atomized from a sample.
GFAA spectrometry instruments have the following basic features: 1. a source of light (lamp) that emits resonance line radiation; 2. an atomization chamber (graphite tube) in which the sample is vaporized; 3. a monochromator for selecting only one of the characteristic wavelengths (visible or ultraviolet) of the element of interest; 4. a detector, generally a photomultiplier tube (light ...
In atomic absorption spectroscopy, light of a predetermined wavelength is passed through a collection of atoms. If the wavelength of the source light has energy corresponding to the energy difference between two energy levels in the atoms, a portion of the light will be absorbed.
For atoms in the gas phase the principal effects are Doppler and pressure broadening. Lines are relatively sharp on the scale of measurement so that applications such as atomic absorption spectroscopy (AAS) and Inductively coupled plasma atomic emission spectroscopy (ICP) are used for elemental analysis. Atoms also have distinct x-ray spectra ...
Basic diagram of a hollow-cathode lamp Hollow-cathode lamps from an atomic absorption spectrometer. A hollow-cathode lamp (HCL) is type of cold cathode lamp used in physics and chemistry as a spectral line source (e.g. for atomic absorption spectrometers) and as a frequency tuner for light sources such as lasers.
The Paschen–Back effect is the splitting of atomic energy levels in the presence of a strong magnetic field. This occurs when an external magnetic field is sufficiently strong to disrupt the coupling between orbital ( L → {\displaystyle {\vec {L}}} ) and spin ( S → {\displaystyle {\vec {S}}} ) angular momenta.
Saturated absorption spectroscopy measures the transition frequency of an atom or molecule between its ground state and an excited state.In saturated absorption spectroscopy, two counter-propagating, overlapped laser beams are sent through a sample of atomic gas.
Atomic absorption spectroscopy and atomic emission spectroscopy involve visible and ultraviolet light. These absorptions and emissions, often referred to as atomic spectral lines, are due to electronic transitions of outer shell electrons as they rise and fall from one electron orbit to another.