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Nitrocellulose (also known as cellulose nitrate, flash paper, flash cotton, guncotton, pyroxylin and flash string, depending on form) is a highly flammable compound formed by nitrating cellulose through exposure to a mixture of nitric acid and sulfuric acid.
The first step is transforming raw cellulose into nitrocellulose by conducting a nitration reaction. This is achieved by exposing the cellulose fibers to an aqueous solution of nitric acid; the hydroxyl groups (-OH) will then be replaced with nitrate groups (-ONO 2) on the cellulose chain. The reaction can produce mixed products, depending on ...
HMG Heat and Waterproof Adhesive (also known as HMG or HMG adhesive) is a brand of cellulose nitrate adhesive manufactured by H Marcel Guest Ltd. It is one of the most popular cellulose nitrate adhesives used in conservation and restoration work, and is used on materials such as metal, wood, glass, and pottery.
A film base is a transparent substrate which acts as a support medium for the photosensitive emulsion that lies atop it. Despite the numerous layers and coatings associated with the emulsion layer, the base generally accounts for the vast majority of the thickness of any given film stock.
Cellulose acetate film, made from cellulose diacetate and later cellulose triacetate, was introduced in 1934 as a replacement for the cellulose nitrate film stock that had previously been standard. When exposed to heat or moisture, acids in the film base begin to deteriorate to an unusable state, releasing acetic acid with a characteristic ...
Cellulose acetate is also known as "safety" film and started to replace nitrate film in still photography in the 1920s. [1] There are several types of acetate that were produced after 1925, which include diacetate (c. 1923 – c. 1955), acetate propionate (1927 – c. 1949), acetate butyrate (1936–present), and triacetate (c. 1950 – present). [1]
Originally the highly flammable cellulose nitrate was used. In the 1930s, film manufacturers introduced "safety film" with a cellulose triacetate plastic base. All amateur film stocks were safety film, but the use of nitrate persisted for professional releases.
The development of cellulose nitrate plastic in 1846 led to the patent of castor oil in 1856 for use as the first plasticizer. In 1870, camphor became the more favored plasticizer for cellulose nitrate. Phthalates were first introduced in the 1920s and quickly replaced the volatile and odorous camphor.