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Iron(II) perchlorate is the inorganic compound with the formula Fe(ClO 4) 2 ·6H 2 O. A green, water-soluble solid, it is produced by the reaction of iron metal with dilute perchloric acid followed by evaporation of the solution: [ 3 ]
Potassium ferrioxalate contains the iron(III) complex [Fe(C 2 O 4) 3] 3−. In chemistry, iron(III) or ferric refers to the element iron in its +3 oxidation state. Ferric chloride is an alternative name for iron(III) chloride (FeCl 3). The adjective ferrous is used instead for iron(II) salts, containing the cation Fe 2+.
Iron(III) chloride forms a 1:2 adduct with Lewis bases such as triphenylphosphine oxide; e.g., FeCl 3 (OP(C 6 H 5) 3) 2. The related 1:2 complex FeCl 3 (OEt 2) 2, where Et = C 2 H 5), has been crystallized from ether solution. [14] Iron(III) chloride also reacts with tetraethylammonium chloride to give the yellow salt of the tetrachloroferrate ...
Perchlorate concentration was the highest in Chilean nitrate, ranging from 3.3 to 3.98%. [51] Perchlorate in the solid fertilizer ranged from 0.7 to 2.0 mg g −1, variation of less than a factor of 3 and it is estimated that sodium nitrate fertilizers derived from Chilean caliche contain approximately 0.5–2 mg g −1 of perchlorate anion. [74]
Green rust is a generic name for various green crystalline chemical compounds containing iron(II) and iron(III) cations, the hydroxide (OH −) anion, and another anion such as carbonate (CO 2− 3), chloride (Cl −), or sulfate (SO 2− 4), in a layered double hydroxide (LDH) structure. The most studied varieties are the following: [1]
Ferrous carbonate can be prepared also from solutions of an iron(II) salt, such as iron(II) perchlorate, with sodium bicarbonate, releasing carbon dioxide: [6] Fe (ClO 4) 2 + 2 NaHCO 3 → FeCO 3 + 2 NaClO 4 + CO 2 + H 2 O. Sel and others used this reaction (but with FeCl 2 instead of Fe (ClO 4) 2) at 0.2 M to prepare amorphous FeCO 3. [7] Care ...
The adjective ferric is used instead for iron(III) salts, containing the cation Fe 3+. The word ferrous is derived from the Latin word ferrum , meaning "iron". In ionic compounds (salts), such an atom may occur as a separate cation (positive ion) abbreviated as Fe 2+ , although more precise descriptions include other ligands such as water and ...
Iron(II) chloride, also known as ferrous chloride, is the chemical compound of formula FeCl 2.It is a paramagnetic solid with a high melting point. The compound is white, but typical samples are often off-white.