Search results
Results From The WOW.Com Content Network
Manganese(III) chloride is the hypothetical inorganic compound with the formula MnCl 3. The existence of this binary halide has not been demonstrated. [ 1 ] [ 2 ] Nonetheless, many derivatives of MnCl 3 are known, such as MnCl 3 (THF) 3 and the bench-stable MnCl 3 (OPPh 3 ) 2 .
Manganese(III) chloride – MnCl 3; Manganese(III) oxide – Mn 2 O 3; Manganese(IV) fluoride – MnF 4; Manganese(IV) oxide (manganese dioxide) – MnO 2;
Jacobsen's catalyst is the common name for N,N'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride, a coordination compound of manganese and a salen-type ligand. It is used as an asymmetric catalyst in the Jacobsen epoxidation , which is renowned for its ability to enantioselectively transform prochiral alkenes ...
Manganese chloride may refer to: Manganese(II) chloride (manganous chloride, manganese dichloride), MnCl 2 , stable pink solid Manganese(III) chloride (manganic chloride, manganese trichloride), MnCl 3 , hypothetical chemical compound
Manganese(III) acetate is an oxidant useful in organic synthesis. Solid compounds of manganese(III) are characterized by its strong purple-red color and a preference for distorted octahedral coordination resulting from the Jahn-Teller effect. [34] Aqueous solution of KMnO 4 illustrating the deep purple of Mn(VII) as it occurs in permanganate
Bis(triphenylphosphineoxide) manganese(III) chloride is a coordination complex of manganese(III) chloride. Unlike most compounds containing "Mn(III)Cl 3", [MnCl 3 (OPPh 3) 2] can be stored under normal laboratory conditions. [1] It is a blue, paramagnetic solid.
In the solid state below 159 °C, manganocene adopts a polymeric structure with every manganese atom coordinated by three cyclopentadienyl ligands, two of which are bridging ligands. Above 159 °C, the solid changes color from amber to pink and the polymer converts to the structure of a normal sandwich complex, i.e., the molecule Mn(η 5-C 5 H ...
Manganese may also form mixed oxides with other metals : Bixbyite, (Fe III,Mn III) 2 O 3, a manganese(III) iron(III) oxide mineral; Jacobsite, Mn II Fe III 2 O 4, a manganese(II) iron(III) oxide mineral; Columbite, (Fe II,Mn II)Nb 2 O 6, a niobate of iron(II) and manganese(II) Tantalite, (Fe II,Mn II)Ta 2 O 6, a tantalum(V) mineral group close ...