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In chemistry, yield, also known as reaction yield or chemical yield, refers to the amount of product obtained in a chemical reaction. [1] Yield is one of the primary factors that scientists must consider in organic and inorganic chemical synthesis processes. [2] In chemical reaction engineering, "yield", "conversion" and "selectivity" are terms ...
Stoichiometry. A stoichiometric diagram of the combustion reaction of methane. Stoichiometry (/ ˌstɔɪkiˈɒmɪtri /) is the relationships among the weights of reactants and products before, during, and following chemical reactions. Stoichiometry is founded on the law of conservation of mass where the total mass of the reactants equals the ...
Limiting reagent. The limiting reagent (or limiting reactant or limiting agent) in a chemical reaction is a reactant that is totally consumed when the chemical reaction is completed. [1][2] The amount of product formed is limited by this reagent, since the reaction cannot continue without it. If one or more other reagents are present in excess ...
Conversion and its related terms yield and selectivity are important terms in chemical reaction engineering.They are described as ratios of how much of a reactant has reacted (X — conversion, normally between zero and one), how much of a desired product was formed (Y — yield, normally also between zero and one) and how much desired product was formed in ratio to the undesired product(s) (S ...
Percentage yield is calculated by dividing the amount of the obtained desired product by the theoretical yield. [6] In a chemical process, the reaction is usually reversible, thus reactants are not completely converted into products; some reactants are also lost by undesired side reaction.
Collision theory. Reaction rate tends to increase with concentration phenomenon explained by collision theory. Collision theory is a principle of chemistry used to predict the rates of chemical reactions. It states that when suitable particles of the reactant hit each other with the correct orientation, only a certain amount of collisions ...
The Van 't Hoff equation relates the change in the equilibrium constant, Keq, of a chemical reaction to the change in temperature, T, given the standard enthalpy change, ΔrH⊖, for the process. The subscript means "reaction" and the superscript means "standard". It was proposed by Dutch chemist Jacobus Henricus van 't Hoff in 1884 in his book ...
All chemical transformations pass through an unstable structure called the transition state, which is poised between the chemical structures of the substrates and products. The transition states for chemical reactions are proposed to have lifetimes near 10 −13 seconds, on the order of the time of a single bond vibration. No physical or ...