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Phosphorus comprises 0.1% by mass of the average rock [12] (while, for perspective, its typical concentration in vegetation is 0.03% to 0.2%), [13] and consequently there are quadrillions of tons of phosphorus in Earth's 3×10 19-ton crust, [14] albeit at predominantly lower concentration than the deposits counted as reserves, which are ...
Chemical formula. H 4 O 7 PV (dihydrate) Molar mass: 197.94 (dihydrate) Appearance yellow solid (dihydrate) Solubility in water. insoluble
The phosphomolybdate ion, [PMo 12 O 40] 3−. Ammonium phosphomolybdate is the inorganic salt of phosphomolybdic acid with the chemical formula (NH 4) 3 PMo 12 O 40. The salt contains the phosphomolybdate anion, a well known heteropolymetalate of the Keggin structural class.
4 Ca 5 (PO 4) 3 F + 18 SiO 2 + 30 C → 3 P 4 + 30 CO + 18 CaSiO 3 + 2 CaF 2 2 Ca 3 (PO 4) 2 + 6 SiO 2 + 10 C → 6 CaSiO 3 + 10 CO + P 4. Side products from the thermal process include ferrophosphorus, a crude form of Fe 2 P, resulting from iron impurities in the mineral precursors. The silicate slag is a useful construction material.
The "backbone" of a polyphosphoric acid molecule is a chain of alternating P and O atoms. Each extra orthophosphoric unit that is condensed adds 1 extra H atom, 1 extra P atom, and 3 extra O atoms. The general formula of a polyphosphoric acid is H n+2 P n O 3n+1 or HO[−P(O)(OH)−O−] n H.
Ammonium phosphate is the inorganic compound with the formula (NH 4) 3 PO 4.It is the ammonium salt of orthophosphoric acid. A related "double salt", (NH 4) 3 PO 4. (NH 4) 2 HPO 4 is also recognized but is impractical to use.
Ca 5 (PO 4) 3 F + 5 H 2 SO 4 → 3 H 3 PO 4 + 5 CaSO 4 + HF. Calcium sulfate (gypsum, CaSO 4) is a by-product, which is removed as phosphogypsum. The hydrogen fluoride (HF) gas is streamed into a wet (water) scrubber producing hydrofluoric acid. In both cases the phosphoric acid solution usually contains 23–33% P 2 O 5 (32–46% H 3 PO 4).
It is a cyclic polyphosphate with the formula Na 6 [(PO 3) 6]. Crystalline high molecular weight polyphosphates include Kurrol's salt and Maddrell's salt (CAS#10361-03-2). These species have the formula [NaPO 3] n [NaPO 3 (OH)] 2 where n can be as great as 2000, and it is a white