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The throttling process is a good example of an isoenthalpic process in which significant changes in pressure and temperature can occur to the fluid, and yet the net sum the associated terms in the energy balance is null, thus rendering the transformation isoenthalpic. The lifting of a relief (or safety) valve on a pressure vessel is an example ...
E.g. throttling from 200 bar and 300 K (point a in fig. 2) follows the isenthalpic (line of constant specific enthalpy) of 430 kJ/kg. At 1 bar it results in point b which has a temperature of 270 K. So throttling from 200 bar to 1 bar gives a cooling from room temperature to below the freezing point of water.
The path or series of states through which a system passes from an initial equilibrium state to a final equilibrium state [1] and can be viewed graphically on a pressure-volume (P-V), pressure-temperature (P-T), and temperature-entropy (T-s) diagrams. [2] There are an infinite number of possible paths from an initial point to an end point in a ...
[1] Working fluids are often categorized on the basis of the shape of their T–s diagram. An isentropic process is depicted as a vertical line on a T–s diagram, whereas an isothermal process is a horizontal line. [2] Example T–s diagram for a thermodynamic cycle taking place between a hot reservoir (T H) and a cold reservoir (T C).
An example of a cycle of idealized thermodynamic processes which make up the Stirling cycle. A quasi-static thermodynamic process can be visualized by graphically plotting the path of idealized changes to the system's state variables. In the example, a cycle consisting of four quasi-static processes is shown.
As an example, consider the conjugate pair. The pressure acts as a generalized force – pressure differences force a change in volume, and their product is the energy lost by the system due to mechanical work. Pressure is the driving force, volume is the associated displacement, and the two form a pair of conjugate variables.
For example, values of the Gibbs energy obtained from high-temperature equilibrium emf methods must be identical to those calculated from calorimetric measurements of the enthalpy and entropy values. The database provider must use recognized data analysis procedures to resolve differences between data obtained by different types of experiments.
For example, when a machine (not a part of the system) lifts a system upwards, some energy is transferred from the machine to the system. The system's energy increases as work is done on the system and in this particular case, the energy increase of the system is manifested as an increase in the system's gravitational potential energy. Work ...