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Thiocyanate [6] is known to be an important part in the biosynthesis of hypothiocyanite by a lactoperoxidase. [7] [8] [9] Thus the complete absence of thiocyanate or reduced thiocyanate [10] in the human body, (e.g., cystic fibrosis) is damaging to the human host defense system.
Organic thiocyanates are hydrolyzed to thiocarbamates in the Riemschneider thiocarbamate synthesis. Electrochemical reduction typically converts thiocyanates to thioates and cyanide, although sometimes it can replace the thiocyanate group as a whole with hydride. [8] Some thiocyanates isomerize to the isothiocyanates.
Sodium thiocyanate (sometimes called sodium sulphocyanide) is the chemical compound with the formula NaSCN. This colorless deliquescent salt is one of the main sources of the thiocyanate anion . As such, it is used as a precursor for the synthesis of pharmaceuticals and other specialty chemicals . [ 2 ]
Rhodanese is a mitochondrial enzyme that detoxifies cyanide (CN −) by converting it to thiocyanate (SCN −, also known as "rhodanate"). [1] In enzymatology, the common name is listed as thiosulfate sulfurtransferase (EC 2.8.1.1). [2] The diagram on the right shows the crystallographically-determined structure of rhodanese. It catalyzes the ...
Addition of a thiocyanate salt to a solution containing ferric ions gives a deep red color. The identity of the chromophore remains unknown. [15] The reverse was also used: testing for the presence of thiocyanate by the addition of ferric salts. The 1:1 complex of thiocyanate and iron is deeply red. The effect was first reported in 1826. [16]
The first synthesis of mercury thiocyanate was probably completed in 1821 by Jöns Jacob Berzelius: HgO + 2 HSCN → Hg(SCN) 2 + H 2 O. Evidence for the first pure sample was presented in 1866 prepared by a chemist named Otto Hermes. [2] It is prepared by treating solutions containing mercury(II) and thiocyanate ions.
Barium thiocyanate is prepared by mixing barium hydroxide and ammonium thiocyanate in water. [4] 2 NH 4 SCN + Ba(OH) 2 → Ba(SCN) 2 + 2 NH 3 + 2 H 2 O. According to X-ray crystallography, the anhydrous salt is a coordination polymer. The Ba 2+ ions are each bonded to eight thiocyanate anions, with four Ba-S and four Ba-N
TMSNCS used for the synthesis of 2-amino-1,3,4-oxadiazoles. The TMSNCS reagent assists in the production of the thiosemicarbazide and the subsequent reaction (cyclodesulfurization of thiosemicarbazides under basic conditions in the presence of I2/KI) results in 2-amino-1,3,4-oxadiazoles in high yields (79–94%). [ 9 ]