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Rate 1 is the rate of effusion for the first gas. (volume or number of moles per unit time). Rate 2 is the rate of effusion for the second gas. M 1 is the molar mass of gas 1 M 2 is the molar mass of gas 2. Graham's law states that the rate of diffusion or of effusion of a gas is inversely proportional to the square root of its molecular weight.
Diffusivity, mass diffusivity or diffusion coefficient is usually written as the proportionality constant between the molar flux due to molecular diffusion and the negative value of the gradient in the concentration of the species. More accurately, the diffusion coefficient times the local concentration is the proportionality constant between ...
In engineering, the mass transfer coefficient is a diffusion rate constant that relates the mass transfer rate, mass transfer area, and concentration change as driving force: [1] = ˙ Where: is the mass transfer coefficient [mol/(s·m 2)/(mol/m 3)], or m/s
The turbulent Schmidt number is commonly used in turbulence research and is defined as: [3] = where: is the eddy viscosity in units of (m 2 /s); is the eddy diffusivity (m 2 /s).; The turbulent Schmidt number describes the ratio between the rates of turbulent transport of momentum and the turbulent transport of mass (or any passive scalar).
The self-diffusion coefficient of water has been experimentally determined with high accuracy and thus serves often as a reference value for measurements on other liquids. The self-diffusion coefficient of neat water is: 2.299·10 −9 m 2 ·s −1 at 25 °C and 1.261·10 −9 m 2 ·s −1 at 4 °C. [2]
Diffusivity is a rate of diffusion, a measure of the rate at which particles or heat or fluids can spread. It is measured differently for different mediums. Diffusivity may refer to: Thermal diffusivity, diffusivity of heat; Diffusivity of mass: Mass diffusivity, molecular diffusivity (often called "diffusion coefficient")
Gaseous diffusion is based on Graham's law, which states that the rate of effusion of a gas is inversely proportional to the square root of its molecular mass. For example, in a box with a microporous membrane containing a mixture of two gases, the lighter molecules will pass out of the container more rapidly than the heavier molecules, if the ...
Dimensionless numbers (or characteristic numbers) have an important role in analyzing the behavior of fluids and their flow as well as in other transport phenomena. [1] They include the Reynolds and the Mach numbers, which describe as ratios the relative magnitude of fluid and physical system characteristics, such as density, viscosity, speed of sound, and flow speed.
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