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DNA ligase is able to form a phosphodiester bond between the nucleotides on each side of the gap. [2] Phosphodiesters are negatively charged at pH 7. [5] The negative charge attracts histones, metal cations such as magnesium, and polyamines [needs citation]. Repulsion between these negative charges influences the conformation of the polynucleic ...
Esterification is the general name for a chemical reaction in which two reactants (typically an alcohol and an acid) form an ester as the reaction product. Esters are common in organic chemistry and biological materials, and often have a pleasant characteristic, fruity odor. This leads to their extensive use in the fragrance and flavor industry.
The ester linkage is formed between the N-hydroxyphthalimide and a carboxylic acid by elimination of water, the coupling achieved with N,N′-dicyclohexylcarbodiimide (DCC). For peptide synthesis, the N-terminus of the growing peptide is protected with tert -butyloxycarbonyl while its C-terminus (Z–NH–CH(R)–COOH) is coupled to N ...
The ester bond is formed between the carboxylate group of a fatty acid and the hydroxyl group of cholesterol. Cholesteryl esters have a lower solubility in water due to their increased hydrophobicity. Esters are formed by replacing at least one –OH (hydroxyl) group with an –O–alkyl (alkoxy) group.
This linkage is an ester bond that chemically binds the carboxyl group of an amino acid to the terminal 3'-OH group of its cognate tRNA. [7] It has been discovered that the amino acid moiety of a given aa-tRNA provides for its structural integrity; the tRNA moiety dictates, for the most part, how and when the amino acid will be incorporated ...
Ester group (blue) which defines polyesters. This diagram shows just one ester linkage per repeat unit. Polyester is a category of polymers that contain one or two ester linkages in every repeat unit of their main chain. [1] As a specific material, it most commonly refers to a type called polyethylene terephthalate (PET).
Phosphatidylserine is a phospholipid—more specifically a glycerophospholipid—which consists of two fatty acids attached in ester linkage to the first and second carbon of glycerol and serine attached through a phosphodiester linkage to the third carbon of the glycerol.
The carbon–oxygen bond length in these cations is near 1.1 Å (110-112 pm), which is shorter than the 112.8 pm of carbon monoxide and indicates triple-bond character. [ 5 ] [ 6 ] [ 7 ] The carbon centres of acylium ions generally have a linear geometry and sp atomic hybridization , and are best represented by a resonance structure bearing a ...