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Ethanol-water mixtures have less volume than the sum of their individual components at the given fractions. Mixing equal volumes of ethanol and water results in only 1.92 volumes of mixture. [76] [81] Mixing ethanol and water is exothermic, with up to 777 J/mol [82] being released at 298 K. Hydrogen bonding in solid ethanol at −186 °C
Solid–liquid phase change of ethanol–water mixtures Sodium chloride and water form a eutectic mixture whose eutectic point is −21.2 °C [ 8 ] and 23.3% salt by mass. [ 9 ] The eutectic nature of salt and water is exploited when salt is spread on roads to aid snow removal , or mixed with ice to produce low temperatures (for example, in ...
The most pervasive is the application of non-toxic cosolvents with water to produce formulations that can dissolve hydrophobic molecules while maintaining cohesion with biological systems. Common cosolvents for this purpose are ethanol, propylene glycol, glycerine, glycofural, and polyethylene glycols. [7]
Chloroethane is produced by hydrochlorination of ethylene: [11]. C 2 H 4 + HCl → C 2 H 5 Cl. At various times in the past, chloroethane has also been produced from ethanol and hydrochloric acid, from ethane and chlorine, or from ethanol and phosphorus trichloride, but these routes are no longer economical.
By contrast, substances are said to be immiscible if the mixture does not form a solution for certain proportions. For one example, oil is not soluble in water, so these two solvents are immiscible. As another example, butanone (methyl ethyl ketone) is immiscible in water: it is soluble in water up to about 275 grams per liter, but will ...
The addition of a material separation agent, such as benzene to an ethanol/water mixture, changes the molecular interactions and eliminates the azeotrope. Added in the liquid phase, the new component can alter the activity coefficient of various compounds in different ways thus altering a mixture's relative volatility.
The term alcohol originally referred to the primary alcohol ethanol (ethyl alcohol), which is used as a drug and is the main alcohol present in alcoholic drinks. The suffix -ol appears in the International Union of Pure and Applied Chemistry (IUPAC) chemical name of all substances where the hydroxyl group is the functional group with the ...
Excess volume of the mixture of ethanol and water (volume contraction) Heat of mixing of the mixture of ethanol and water Vapor–liquid equilibrium of the mixture of ethanol and water (including azeotrope) Solid–liquid equilibrium of the mixture of ethanol and water (including eutecticum) Miscibility gap in the mixture of dodecane and ethanol