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(9) A second significant side reaction in reactions of ketones and aldehydes is selanylation of the intermediate selenoxide. This process leads to elimination products retaining a carbon-selenium bond, [ 16 ] and is more difficult to prevent than the seleno-Pummerer reaction.
Organic chemistry is a subdiscipline within chemistry involving the scientific study of the structuressssss, properties, and reactions of organic compounds and organic materials, i.e., matter in its various forms that contain carbon atoms. [1]
The following outline is provided as an overview of and topical guide to organic chemistry: Organic chemistry is the scientific study of the structure, properties, composition, reactions, and preparation (by synthesis or by other means) of carbon-based compounds, hydrocarbons, and their derivatives.
Organic chemistry has a strong tradition of naming a specific reaction to its inventor or inventors and a long list of so-called named reactions exists, conservatively estimated at 1000. A very old named reaction is the Claisen rearrangement (1912) and a recent named reaction is the Bingel reaction (1993).
In organic chemistry, syn-and anti-addition are different ways in which substituent molecules can be added to an alkene (R 2 C=CR 2) or alkyne (RC≡CR).The concepts of syn and anti addition are used to characterize the different reactions of organic chemistry by reflecting the stereochemistry of the products in a reaction.
Wiley-Interscience, 3rd edition, 1999, ISBN 0-471-16019-9; Wiley-Interscience, 4th edition, 2007, ISBN 0-471-69754-0; Wiley-Interscience, 5th edition, 2014, ISBN 9781118057483; Description: A comprehensive reference for the usage of protecting groups in organic synthesis. Importance: A reference publication.
In organic chemistry, neighbouring group participation (NGP, also known as anchimeric assistance) has been defined by the International Union of Pure and Applied Chemistry (IUPAC) as the interaction of a reaction centre with a lone pair of electrons in an atom or the electrons present in a sigma or pi bond contained within the parent molecule but not conjugated with the reaction centre.