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Thus, an endothermic reaction generally leads to an increase in the temperature of the system and a decrease in that of the surroundings. [1] The term was coined by 19th-century French chemist Marcellin Berthelot. [3] The term endothermic comes from the Greek แผνδον (endon) meaning 'within' and θερμ- (therm) meaning 'hot' or 'warm'. [4]
The Van 't Hoff equation relates the change in the equilibrium constant, K eq, of a chemical reaction to the change in temperature, T, given the standard enthalpy change, Δ r H โ, for the process. The subscript r {\displaystyle r} means "reaction" and the superscript โ {\displaystyle \ominus } means "standard".
Using the thermochemical equation of variables as above, one gets the following example. + = One must assume that needs to be multiplied by two in order for the thermochemical equation to be used. All the agents in the reaction must then be multiplied by the same coefficient, like so:
The reaction is usually endothermic as heat is required to break chemical bonds in the compound undergoing decomposition. If decomposition is sufficiently exothermic, a positive feedback loop is created producing thermal runaway and possibly an explosion or other chemical reaction. Thermal decomposition is a chemical reaction where heat is a ...
Ammonium chloride is used in a ~5% aqueous solution to work on oil wells with clay swelling problems. Other uses include in hair shampoo, in the glue that bonds plywood, and in cleaning products. In hair shampoo, it is used as a thickening agent in ammonium-based surfactant systems such as ammonium lauryl sulfate. Ammonium chloride is used in ...
If a reaction network has n reactions and m participating molecular species, then the stoichiometry matrix will have correspondingly m rows and n columns. For example, consider the system of reactions shown below: S 1 → S 2 5 S 3 + S 2 → 4 S 3 + 2 S 2 S 3 → S 4 S 4 → S 5. This system comprises four reactions and five different molecular ...
Thermochemistry is the study of the heat energy which is associated with chemical reactions and/or phase changes such as melting and boiling. A reaction may release or absorb energy, and a phase change may do the same. Thermochemistry focuses on the energy exchange between a system and its surroundings in the form of heat. Thermochemistry is ...
In the breakdown of a compound into its constituent parts, the generalized reaction for chemical decomposition is: AB → A + B (AB represents the reactant that begins the reaction, and A and B represent the products of the reaction) An example is the electrolysis of water to the gases hydrogen and oxygen: 2 H 2 O(l) → 2 H 2 (g) + O 2 (g)