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The first organogermanium compound, tetraethylgermane, synthesized by Winkler in 1887, [3] by the reaction of germanium tetrachloride with diethylzinc. More commonly, these Ge(IV) compounds are prepared by alkylation of germanium halides by organolithium and Grignard reagents, including surfaces terminated with Ge-Cl bonds. [4]
Organic germanium hydrides such as isobutylgermane ((CH 3) 2 CHCH 2 GeH 3) were found to be less hazardous and may be used as a liquid substitute for toxic germane gas in semiconductor applications. Many germanium reactive intermediates are known: germyl free radicals, germylenes (similar to carbenes), and germynes (similar to carbynes).
Two oxides of germanium are known: germanium dioxide (GeO 2, germania) and germanium monoxide, (GeO). [4] The dioxide, GeO 2 can be obtained by roasting germanium disulfide (GeS 2) or by allowing elemental germanium to slowly oxidze in air, [5] and is a white powder that is only slightly soluble in water but reacts with alkalis to form germanates. [4]
Chinese customs data show there have been no shipments of wrought and unwrought germanium or gallium to the U.S. this year through October, although it was the fourth and fifth-largest market for ...
Indium Corporation is a materials refiner, smelter, manufacturer, and supplier to the global electronics, semiconductor, thin-film, and thermal management markets.Products include solders and fluxes; brazes; thermal interface materials; sputtering targets; indium, gallium, germanium, and tin metals and inorganic compounds; and NanoFoil.
A number of elements are recovered in flue gas and flue dust in zinc smelters. These include the metal cadmium and the semi-metals gallium and germanium. In 1970, for every ton of zinc produced at a US smelter, there were also recovered 4.2 kilograms of cadmium, 53 grams of germanium, 18 grams of indium, and 2.9 grams of thallium. [13]