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According to ASHRAE standard 34, the R-number of a chemical refrigerant is assigned systematically according to its molecular structure and has between two and four digits. If there are carbon -carbon multiple bonds , there are four digits in all: the number of these bonds is the first digit and the number of carbon atoms minus one (C-1) is next.
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Class 1: This class includes refrigerants that cool by phase change (typically boiling), using the refrigerant's latent heat. Class 2: These refrigerants cool by temperature change or 'sensible heat', the quantity of heat being the specific heat capacity x the temperature change. They are air, calcium chloride brine, sodium chloride brine ...
The number after the R is a refrigerant class number developed by DuPont to systematically identify single halogenated hydrocarbons, as well as other refrigerants besides halocarbons. Most uses of CFCs are now banned or severely restricted by the Montreal Protocol of August 1987, as they have been shown to be responsible for ozone depletion. [6]
Natural refrigerants are one of the potential options for replacement of HFCs, and are growing in usage and popularity as a result. The natural refrigerant industry is expected to have a compounded annual growth rate of 8.5% over the next 4 years, [10] and is expected to become a US$2.88 billion industry by 2027. [2]
Many refrigerants in the HFO class are inherently stable chemically and inert, non toxic, and non-flammable or mildly flammable. Many HFOs have the proper freezing and boiling points to be useful for refrigeration at common temperatures.