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In physical chemistry, the Arrhenius equation is a formula for the temperature dependence of reaction rates.The equation was proposed by Svante Arrhenius in 1889, based on the work of Dutch chemist Jacobus Henricus van 't Hoff who had noted in 1884 that the van 't Hoff equation for the temperature dependence of equilibrium constants suggests such a formula for the rates of both forward and ...
In chemistry, volatility is a material quality which describes how readily a substance vaporizes. At a given temperature and pressure , a substance with high volatility is more likely to exist as a vapour , while a substance with low volatility is more likely to be a liquid or solid .
Activation energy can be thought of as the magnitude of the potential barrier (sometimes called the energy barrier) separating minima of the potential energy surface pertaining to the initial and final thermodynamic state. For a chemical reaction to proceed at a reasonable rate, the temperature of the system should be high enough such that ...
In chemistry, the law of mass action is the proposition that the rate of a chemical reaction is directly proportional to the product of the activities or concentrations of the reactants. [1] It explains and predicts behaviors of solutions in dynamic equilibrium.
A quantity is subject to exponential decay if it decreases at a rate proportional to its current value. Symbolically, this process can be expressed by the following differential equation , where N is the quantity and λ ( lambda ) is a positive rate called the exponential decay constant , disintegration constant , [ 1 ] rate constant , [ 2 ] or ...
In chemistry, the mass fraction of a substance within a mixture is the ratio (alternatively denoted ) of the mass of that substance to the total mass of the mixture. [1] Expressed as a formula, the mass fraction is:
This energy barrier is known as activation energy (∆G ≠) and the rate of reaction is dependent on the height of this barrier. A low energy barrier corresponds to a fast reaction and high energy barrier corresponds to a slow reaction. A reaction is in equilibrium when the rate of forward reaction is equal to the rate of reverse reaction.
Titer (American English) or titre (British English) is a way of expressing concentration. [1] Titer testing employs serial dilution to obtain approximate quantitative information from an analytical procedure that inherently only evaluates as positive or negative.