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Pitzer equations [1] are important for the understanding of the behaviour of ions dissolved in natural waters such as rivers, lakes and sea-water. [2] [3] [4] They were first described by physical chemist Kenneth Pitzer. [5]
Different disciplines have different conventions as to whether absorbance is decadic (10-based) or Napierian (e-based), i.e., defined with respect to the transmission via common logarithm (log 10) or a natural logarithm (ln). The molar absorption coefficient is usually decadic.
Substance Formula 0 °C 10 °C 20 °C 30 °C 40 °C 50 °C 60 °C 70 °C 80 °C 90 °C 100 °C Barium acetate: Ba(C 2 H 3 O 2) 2: 58.8: 62: 72: 75: 78.5: 77: 75
The term phosphate is also used in organic chemistry for the functional groups that result when one or more of the hydrogens are replaced by bonds to other groups. These acids, together with their salts and esters , include some of the best-known compounds of phosphorus, of high importance in biochemistry , mineralogy , agriculture , pharmacy ...
Relationship of phosphate to nitrate uptake for photosynthesis in various regions of the ocean. Note that nitrate is more often limiting than phosphate. The Redfield ratio or Redfield stoichiometry is the consistent atomic ratio of carbon, nitrogen and phosphorus found in marine phytoplankton and throughout the deep oceans.
In biochemistry and medicinal chemistry, phosphonate groups are used as stable bioisosteres for phosphate, such as in the antiviral nucleotide analog, Tenofovir, one of the cornerstones of anti-HIV therapy. And there is an indication that phosphonate derivatives are "promising ligands for nuclear medicine." [2]
The pyrophosphate anion has the structure P 2 O 4− 7, and is an acid anhydride of phosphate. It is unstable in aqueous solution and hydrolyzes into inorganic phosphate: P 2 O 4− 7 + H 2 O → 2 HPO 2− 4. or in biologists' shorthand notation: PP i + H 2 O → 2 P i + 2 H +
Phosphate minerals contain the phosphate, PO 4 3−, anion. In standard mineral classification systems (in both the Dana [1] and Strunz [2] systems) the phosphate class includes the arsenates , vanadates and the polyvanadates.