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Atomic emission spectroscopy (AES) is a method of chemical analysis that uses the intensity of light emitted from a flame, plasma, arc, or spark at a particular wavelength to determine the quantity of an element in a sample.
Flame photometry is a type of atomic emission spectroscopy. It is also known as flame emission spectroscopy. [1] [2] A photoelectric flame photometer is an instrument used in inorganic chemical analysis to determine the concentration of certain metal ions, among them sodium, potassium, lithium, and calcium. [3]
The nature of the excited and ground states depends only on the element. Ordinarily, there are no bonds to be broken, and molecular orbital theory is not applicable. The emission spectrum observed in flame test is also the basis of flame emission spectroscopy, atomic emission spectroscopy, and flame photometry. [4] [13]
The simplest method is to heat the sample to a high temperature, after which the excitations are produced by collisions between the sample atoms. This method is used in flame emission spectroscopy, and it was also the method used by Anders Jonas Ångström when he discovered the phenomenon of discrete emission lines in the 1850s. [1]
Atomic absorption spectroscopy (AAS) is a spectroanalytical procedure for the quantitative measurement of chemical elements. AAS is based on the absorption of light by free metallic ions that have been atomized from a sample. An alternative technique is atomic emission spectroscopy (AES).
Atomic absorption spectroscopy and atomic emission spectroscopy involve visible and ultraviolet light. These absorptions and emissions, often referred to as atomic spectral lines, are due to electronic transitions of outer shell electrons as they rise and fall from one electron orbit to another. Atoms also have distinct x-ray spectra that are ...
It is a type of emission spectroscopy that uses the inductively coupled plasma to produce excited atoms and ions that emit electromagnetic radiation at wavelengths characteristic of a particular element. [1] The plasma is a high temperature source of ionised source gas (often argon).
They are necessary parts of inductively coupled plasma atomic emission spectroscopy , inductively coupled plasma mass spectrometry (ICP-MS), and atomic absorption spectroscopy (AAS). Applications [ edit ]
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