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Ground-level ozone (O 3), also known as surface-level ozone and tropospheric ozone, is a trace gas in the troposphere (the lowest level of the Earth's atmosphere), with an average concentration of 20–30 parts per billion by volume (ppbv), with close to 100 ppbv in polluted areas.
The dominating parameter influencing ozone generation efficiency is the gas temperature, which is controlled by cooling water temperature and/or gas velocity. The cooler the water, the better the ozone synthesis. The lower the gas velocity, the higher the concentration (but the lower the net ozone produced).
If an oxygen atom and an ozone molecule meet, they recombine to form two oxygen molecules: 4. ozone conversion: O 3 + O → 2 O 2. Two oxygen atoms may react to form one oxygen molecule: 5. oxygen recombination: 2O + A → O 2 + A as in reaction 2 (above), A denotes another molecule or atom, like N 2 or O 2 required for the conservation of ...
Triatomic oxygen (ozone, O 3) is a very reactive allotrope of oxygen that is a pale blue gas at standard temperature and pressure. Liquid and solid O 3 have a deeper blue color than ordinary O 2, and they are unstable and explosive. [5] [6] In its gas phase, ozone is destructive to materials like rubber and fabric and is damaging to lung tissue ...
The formation of the ozone layer is also caused by photodissociation. Ozone in the Earth's stratosphere is created by ultraviolet light striking oxygen molecules containing two oxygen atoms (O 2), splitting them into individual oxygen atoms (atomic oxygen). The atomic oxygen then combines with unbroken O 2 to create ozone, O 3. [17]
Ozone-oxygen cycle in the ozone layer. The Earth's ozone layer formed about 500 million years ago, when the neoproterozoic oxygenation event brought the fraction of oxygen in the atmosphere to about 20%. [7] The photochemical mechanisms that give rise to the ozone layer were discovered by the British physicist Sydney Chapman in 1930.
Oxygen began building up in the prebiotic atmosphere at approximately 1.85 Ga during the Neoarchean-Paleoproterozoic boundary, a paleogeological event known as the Great Oxygenation Event (GOE). At current rates of primary production, today's concentration of oxygen could be produced by photosynthetic organisms in 2,000 years. [4]
Recently, singlet oxygen has been found to be a source of biologically-produced ozone: This reaction proceeds through an unusual compound dihydrogen trioxide, also known as trioxidane, (HOOOH), which is an antibody-catalyzed product of singlet oxygen and water. This compound, in turn, disproportionates to ozone and peroxide, providing two ...