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Nitrogen trichloride, also known as trichloramine, is the chemical compound with the formula NCl 3.This yellow, oily, and explosive liquid is most commonly encountered as a product of chemical reactions between ammonia-derivatives and chlorine (for example, in swimming pools).
The electrolyte is usually a solution of water or other solvents in which ions are dissolved. Molten salts such as sodium chloride can also function as electrolytes. When driven by an external voltage applied to the electrodes, the ions in the electrolyte are attracted to an electrode with the opposite charge , where charge-transferring (also ...
Pierre Louis Dulong FRS FRSE (/ d uː ˈ l ɒ ŋ,-ˈ l oʊ ŋ /; French:; 12 February 1785 – 19 July 1838) was a French physicist and chemist.He is remembered today largely for the law of Dulong and Petit, although he was much-lauded by his contemporaries for his studies into the elasticity of steam, conduction of heat, and specific heats of gases.
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To properly fulfil its functions, a supporting electrolyte must meet the following criteria: It must be completely dissociated in aqueous solution, so it is a strong electrolyte with a good conductivity; It must be sufficiently soluble in order to be able to increase the ionic strength of the solution in the experimental conditions to be explored;
A well-known electrosynthesis is the Kolbe electrolysis, in which two carboxylic acids decarboxylate, and the remaining structures bond together:; A variation is called the non-Kolbe reaction when a heteroatom (nitrogen or oxygen) is present at the α-position.
Superconcentrated electrolytes, also known as water-in-salt or solvent-in-salt liquids, usually refer to chemical systems, which are liquid near room temperature and consist of a solvent-to-dissoved salt in a molar ratio near or smaller than ca. 4-8, i.e. where all solvent molecules are coordinated to cations, and no free solvent molecules remain. [1]
Part of the confusion here originates from the fact that one must include d-functions in the basis sets used to describe these compounds (or else unreasonably high energies and distorted geometries result), and the contribution of the d-function to the molecular wavefunction is large.