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The calcium aluminoferrite phase acts as a repository for many of the minor elements in the clinker. Most of the transition metals in the cement are found in the ferrite phase, notably titanium, manganese and zinc. There is also a substantial amount of magnesium and silicon, and because of this, oxides other than CaO, Al 2 O 3 and Fe 2 O
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Zinc ferrite compounds can be prepared by aging solutions of Zn(NO 3) 2, Fe(NO 3) 3, and triethanolamine in the presence and in the absence of hydrazine, [1] or reacting iron oxides and zinc oxide at high temperature. Spinel (Zn, Fe) Fe 2 O 4 appears as a tan-colored solid that is insoluble in water, acids, or diluted alkali. [2]
Below 912 °C (1,674 °F), iron has a body-centered cubic (bcc) crystal structure and is known as α-iron or ferrite.It is thermodynamically stable and a fairly soft metal. α-Fe can be subjected to pressures up to ca. 15 GPa before transforming into a high-pressure form termed ε-Fe discussed below.
The solid-state reaction method is a traditional approach for YIG synthesis, involving the high-temperature firing of a mixture of yttrium and iron oxides. [4] This cost-effective technique can produce pure YIG crystals but requires careful control of temperature and atmosphere to prevent impurities.
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