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  2. Discriminant - Wikipedia

    en.wikipedia.org/wiki/Discriminant

    This expression for the discriminant is often taken as a definition. It makes clear that if the polynomial has a multiple root, then its discriminant is zero, and that, in the case of real coefficients, if all the roots are real and simple, then the discriminant is positive.

  3. Hessian matrix - Wikipedia

    en.wikipedia.org/wiki/Hessian_matrix

    This implies that at a local minimum the Hessian is positive-semidefinite, and at a local maximum the Hessian is negative-semidefinite. For positive-semidefinite and negative-semidefinite Hessians the test is inconclusive (a critical point where the Hessian is semidefinite but not definite may be a local extremum or a saddle point).

  4. Second partial derivative test - Wikipedia

    en.wikipedia.org/wiki/Second_partial_derivative_test

    In cases 1 and 2, the requirement that f xx f yy − f xy 2 is positive at (x, y) implies that f xx and f yy have the same sign there. Therefore, the second condition, that f xx be greater (or less) than zero, could equivalently be that f yy or tr( H ) = f xx + f yy be greater (or less) than zero at that point.

  5. Definite matrix - Wikipedia

    en.wikipedia.org/wiki/Definite_matrix

    In mathematics, a symmetric matrix with real entries is positive-definite if the real number is positive for every nonzero real column vector, where is the row vector transpose of . [1] More generally, a Hermitian matrix (that is, a complex matrix equal to its conjugate transpose) is positive-definite if the real number is positive for every nonzero complex column vector , where denotes the ...

  6. Glossary of chemistry terms - Wikipedia

    en.wikipedia.org/wiki/Glossary_of_chemistry_terms

    Also acid ionization constant or acidity constant. A quantitative measure of the strength of an acid in solution expressed as an equilibrium constant for a chemical dissociation reaction in the context of acid-base reactions. It is often given as its base-10 cologarithm, p K a. acid–base extraction A chemical reaction in which chemical species are separated from other acids and bases. acid ...

  7. Jacobian matrix and determinant - Wikipedia

    en.wikipedia.org/wiki/Jacobian_matrix_and...

    Furthermore, if the Jacobian determinant at p is positive, then f preserves orientation near p; if it is negative, f reverses orientation. The absolute value of the Jacobian determinant at p gives us the factor by which the function f expands or shrinks volumes near p; this is why it occurs in the general substitution rule.

  8. Solvatochromism - Wikipedia

    en.wikipedia.org/wiki/Solvatochromism

    Positive solvatochromism corresponds to a bathochromic shift (or red shift) with increasing solvent polarity. An example of positive solvatochromism is provided by 4,4'-bis(dimethylamino)fuchsone, which is orange in toluene, red in acetone. The main value of the concept of solvatochromism is the context it provides to predict colors of solutions.

  9. Determinant - Wikipedia

    en.wikipedia.org/wiki/Determinant

    For operators in a finite factor, one may define a positive real-valued determinant called the Fuglede−Kadison determinant using the canonical trace. In fact, corresponding to every tracial state on a von Neumann algebra there is a notion of Fuglede−Kadison determinant.