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Methanol toxicity (also methanol poisoning) is poisoning from methanol, characteristically via ingestion. [1] Symptoms may include an altered/decreased level of consciousness, poor or no coordination, vomiting, abdominal pain, and a specific smell on the breath. [1] [2] Decreased vision may start as early as twelve hours after exposure. [2]
If as little as 10 ml of pure methanol is ingested, for example, it can break down into formic acid, which can cause permanent blindness by destruction of the optic nerve, and 30 ml is potentially fatal, [2] although the median lethal dose is typically 100 ml (3.4 fl oz) (i.e. 1–2 ml/kg body weight) of pure methanol. [3]
Methanol and its vapours are flammable. Moderately toxic for small animals – Highly toxic to large animals and humans (in high concentrations) – May be fatal/lethal or cause blindness and damage to the liver, kidneys, and heart if swallowed – Toxicity effects from repeated over exposure have an accumulative effect on the central nervous system, especially the optic nerve – Symptoms may ...
Statements which correspond to related hazards are grouped together by code number, so the numbering is not consecutive. The code is used for reference purposes, for example to help with translations, but it is the actual phrase which should appear on labels and safety data sheets. [4]
Precautionary statements are one of the key elements for the labelling of containers under the GHS, along with: [4] an identification of the product; one or more hazard pictograms (where necessary) a signal word – either Danger or Warning – where necessary; hazard statements, indicating the nature and degree of the risks posed by the product
"EC Safety Phrases" (PDF). ChemBlink.com; Council Directive 2006/102/EC of 20 November 2006 adapting Directive 67/548/EEC on the classification, packaging and labelling of dangerous substances, by reason of the accession of Bulgaria and Romania. No longer in force, Date of end of validity: 31/05/2015; Implicitly repealed by 32008R1272.
The OSHA definition is part of a legal standard, which is the minimum legal requirement. Users or employers are encouraged to apply proper judgment to avoid taking unnecessary risks, even if the only immediate hazard is "reversible", such as temporary pain, disorientation, nausea, or non-toxic contamination.
Methanol is commonly used both because its boiling point is close to that of ethanol and because it is toxic. Another typical denaturant is pyridine. Often the denatured alcohol is dyed with methyl violet. [8] There are several grades of denatured alcohol, but in general the denaturants used are similar.