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According to the rules of IUPAC nomenclature, ketone names are derived by changing the suffix-ane of the parent alkane to -anone. Typically, the position of the carbonyl group is denoted by a number, but traditional nonsystematic names are still generally used for the most important ketones, for example acetone and benzophenone.
A classic example for favoring the keto form can be seen in the equilibrium between vinyl alcohol and acetaldehyde (K = [enol]/[keto] ≈ 3 × 10 −7). In 1,3-diketones, such as acetylacetone (2,4-pentanedione), the enol form is more favored. The acid-catalyzed conversion of an enol to the keto form proceeds by proton transfer from O to carbon.
For example, NaC 6 H 5 CO 2, the sodium salt of benzoic acid (C 6 H 5 COOH), is called sodium benzoate. Where an acid has both a systematic and a common name (like CH 3 COOH, for example, which is known as both acetic acid and as ethanoic acid), its salts can be named from either parent name.
The position alpha to the carbonyl group (C=O) in a ketone is easily halogenated. This is due to its ability to form an enolate (C=C−O −) in basic solution, or an enol (C=C−OH) in acidic solution. An example of alpha halogenation is the mono-bromination of acetone ((CH 3) 2 C=O), carried out under either acidic or basic conditions, to ...
Methyl isobutyl ketone (MIBK, 4-methylpentan-2-one) is an organic compound with the condensed chemical formula (CH 3) 2 CHCH 2 C(O)CH 3. This ketone is a colourless liquid that is used as a solvent for gums, resins, paints, varnishes, lacquers, and nitrocellulose.
In monometallic complexes, aldehydes and ketones can bind to metals in either of two modes, η 1-O-bonded and η 2-C,O-bonded. These bonding modes are sometimes referred to sigma- and pi-bonded. These forms may sometimes interconvert. The sigma bonding mode is more common for higher valence, Lewis-acidic metal centers (e.g., Zn 2+). [1]
p-Dimethylaminobenzophenone is related to Michler's ketone, but with only one amine. [5] Auramine O, a dye, is a salt of the iminium cation [(CH 3) 2 NC 6 H 4] 2 CNH 2 +.Michler's thione, [(CH 3) 2 NC 6 H 4] 2 CS, is prepared by treatment of Michler's ketone with hydrogen sulfide in the presence of acid or sulfideing auramine O. [6] Hydride reduction of Michler's ketone gives 4,4'-bis ...
Pages in category "Ketone solvents" The following 14 pages are in this category, out of 14 total. This list may not reflect recent changes. A. Acetone; Acetophenone; B.