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The Bohr model of the hydrogen atom (Z = 1) or a hydrogen-like ion (Z > 1), where the negatively charged electron confined to an atomic shell encircles a small, positively charged atomic nucleus and where an electron jumps between orbits, is accompanied by an emitted or absorbed amount of electromagnetic energy (hν). [1]
This was a significant step in the development of quantum mechanics. It also described the possibility of atomic energy levels being split by a magnetic field (called the Zeeman effect). Walther Kossel worked with Bohr and Sommerfeld on the Bohr–Sommerfeld model of the atom introducing two electrons in the first shell and eight in the second. [8]
His proposals were based on the then current Bohr model of the atom, in which the electron shells were orbits at a fixed distance from the nucleus. Bohr's original configurations would seem strange to a present-day chemist: sulfur was given as 2.4.4.6 instead of 1s 2 2s 2 2p 6 3s 2 3p 4 (2.8.6). Bohr used 4 and 6 following Alfred Werner's 1893 ...
The Bohr model was later replaced by quantum mechanics in which the electron occupies an atomic orbital rather than an orbit, but the allowed energy levels of the hydrogen atom remained the same as in the earlier theory. Spectral emission occurs when an electron transitions, or jumps, from a higher energy state to a lower energy state.
The energy level of the bonding orbitals is lower, and the energy level of the antibonding orbitals is higher. For the bond in the molecule to be stable, the covalent bonding electrons occupy the lower energy bonding orbital, which may be signified by such symbols as σ or π depending on the situation.
An electron in a Bohr model atom, moving from quantum level n = 3 to n = 2 and releasing a photon.The energy of an electron is determined by its orbit around the atom, The n = 0 orbit, commonly referred to as the ground state, has the lowest energy of all states in the system.
The Bohr model of the chemical bond took into account the Coulomb repulsion - the electrons in the ring are at the maximum distance from each other. [2] Thus, according to this model, the methane molecule is a regular tetrahedron, in which center the carbon nucleus locates, and in the corners - the nucleus of hydrogen. The chemical bond between ...
The principal quantum number was first created for use in the semiclassical Bohr model of the atom, distinguishing between different energy levels. With the development of modern quantum mechanics, the simple Bohr model was replaced with a more complex theory of atomic orbitals. However, the modern theory still requires the principal quantum ...