When.com Web Search

  1. Ads

    related to: oxymercuration reduction of alkenes 1 x 2 5 8 label template

Search results

  1. Results From The WOW.Com Content Network
  2. Oxymercuration reaction - Wikipedia

    en.wikipedia.org/wiki/Oxymercuration_reaction

    In organic chemistry, the oxymercuration reaction is an electrophilic addition reaction that transforms an alkene (R 2 C=CR 2) into a neutral alcohol. In oxymercuration, the alkene reacts with mercuric acetate (AcO−Hg−OAc) in aqueous solution to yield the addition of an acetoxymercury (−HgOAc) group and a hydroxy (−OH) group across the ...

  3. McMurry reaction - Wikipedia

    en.wikipedia.org/wiki/McMurry_reaction

    This reductive coupling can be viewed as involving two steps. First is the formation of a pinacolate (1,2-diolate) complex, a step which is equivalent to the pinacol coupling reaction. The second step is the deoxygenation of the pinacolate, which yields the alkene, this second step exploits the oxophilicity of titanium.

  4. Hydrohalogenation - Wikipedia

    en.wikipedia.org/wiki/Hydrohalogenation

    A hydrohalogenation reaction is the electrophilic addition of hydrogen halides like hydrogen chloride or hydrogen bromide to alkenes to yield the corresponding haloalkanes. [ 1 ] [ 2 ] [ 3 ] If the two carbon atoms at the double bond are linked to a different number of hydrogen atoms, the halogen is found preferentially at the carbon with fewer ...

  5. Syn and anti addition - Wikipedia

    en.wikipedia.org/wiki/Syn_and_anti_addition

    [2] 1,2-disubstituted Cycloalkene undergoing syn and anti addition. Syn addition is the addition of two substituents to the same side (or face) of a double bond or triple bond, resulting in a decrease in bond order but an increase in number of substituents. [3] Generally the substrate will be an alkene or alkyne.

  6. Chugaev elimination - Wikipedia

    en.wikipedia.org/wiki/Chugaev_elimination

    The Chugaev elimination is a chemical reaction that involves the elimination of water from alcohols to produce alkenes.The intermediate is a xanthate.It is named for its discoverer, the Russian chemist Lev Aleksandrovich Chugaev (1873–1922), who first reported the reaction sequence in 1899.

  7. Mukaiyama hydration - Wikipedia

    en.wikipedia.org/wiki/Mukaiyama_hydration

    A recent review by Shenvi and coworkers, [8] proposed that the Mukaiyama hydration operates via the same principles as metal hydride hydrogen atom transfer (MH HAT), elucidated by Jack Halpern and Jack R. Norton in their studies on hydrogenation of anthracenes by syngas and Co 2 (CO) 8 [9] and the chemistry of vitamin B 12 mimics, [10 ...

  8. Hydroboration–oxidation reaction - Wikipedia

    en.wikipedia.org/wiki/Hydroboration–oxidation...

    The reaction thus provides a more stereospecific and complementary regiochemical alternative to other hydration reactions such as acid-catalyzed addition and the oxymercuration–reduction process. The reaction was first reported by Herbert C. Brown in the late 1950s [2] and it was recognized in his receiving the Nobel Prize in Chemistry in 1979.

  9. Grieco elimination - Wikipedia

    en.wikipedia.org/wiki/Grieco_elimination

    The Grieco elimination is an organic reaction describing the elimination reaction of an aliphatic primary alcohol through a selenide to a terminal alkene. [1] [2] It is named for Paul Grieco. The alcohol first reacts with o-nitrophenylselenocyanate and tributylphosphine to form a selenide via a nucleophilic substitution on the electron ...