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BET model of multilayer adsorption, that is, a random distribution of sites covered by one, two, three, etc., adsorbate molecules. The concept of the theory is an extension of the Langmuir theory, which is a theory for monolayer molecular adsorption, to multilayer adsorption with the following hypotheses:
Differential adhesion hypothesis (DAH) is a hypothesis that explains cellular movement during morphogenesis with thermodynamic principles. In DAH tissues are treated as liquids consisting of mobile cells whose varying degrees of surface adhesion cause them to reorganize spontaneously to minimize their interfacial free energy. [1]
The solubility in water depends on the type of salt. Sodium chloride can be dissolved in cold water to a concentration of 357 g∙l −1. Not only solubility differs between salts but also the conductivity. When performing a Bresle method test, not only sodium chloride is dissolved but also all other salts present on the surface.
To incorporate the effect of adhesion in Hertzian contact, Johnson, Kendall, and Roberts [5] formulated the JKR theory of adhesive contact using a balance between the stored elastic energy and the loss in surface energy. The JKR model considers the effect of contact pressure and adhesion only inside the area of contact.
A water model is defined by its geometry, together with other parameters such as the atomic charges and Lennard-Jones parameters. In computational chemistry, a water model is used to simulate and thermodynamically calculate water clusters, liquid water, and aqueous solutions with explicit solvent, often using molecular dynamics or Monte Carlo methods.
One example of a superhydrophobic surface in nature is the Lotus leaf. [12] Lotus leaves have a typical contact angle of θ ∼ 160 ∘ {\displaystyle \theta \sim 160^{\circ }} , ultra low water adhesion due to minimal contact areas, and a self cleaning property which is characterised by the Cassie-Baxter equation. [ 13 ]
In adhesion tests per ASTM D4541, in which an aluminum stud is bonded to the test surface and the stud is pulled in the direction normal to the surface, both surfaces of the failure interface were analyzed by X-ray photoelectron spectroscopy (XPS). F/C ratio was used as an indicator of the failure mode: F/C of zero corresponds to failure in the ...
Example 1. The linear-reservoir model (or Nash model) is widely used for rainfall-runoff analysis. The model uses a cascade of linear reservoirs along with a constant first-order storage coefficient, K, to predict the outflow from each reservoir (which is then used as the input to the next in the series).