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Vaporization. Vaporization (or vapo (u)risation) of an element or compound is a phase transition from the liquid phase to vapor. [1] There are two types of vaporization: evaporation and boiling. Evaporation is a surface phenomenon, whereas boiling is a bulk phenomenon (a phenomenon in which the whole object or substance is involved in the process).
Evaporation is a type of vaporization that occurs on the surface of a liquid as it changes into the gas phase. [1] A high concentration of the evaporating substance in the surrounding gas significantly slows down evaporation, such as when humidity affects rate of evaporation of water. [2] When the molecules of the liquid collide, they transfer ...
The enthalpy of vaporization is a function of the pressure and temperature at which the transformation (vaporization or evaporation) takes place. The enthalpy of vaporization is often quoted for the normal boiling temperature of the substance. Although tabulated values are usually corrected to 298 K, that correction is often smaller than the ...
Water vapor, water vapour or aqueous vapor is the gaseous phase of water. It is one state of water within the hydrosphere. Water vapor can be produced from the evaporation or boiling of liquid water or from the sublimation of ice. Water vapor is transparent, like most constituents of the atmosphere. [1] Under typical atmospheric conditions ...
Antoine equation. The Antoine equation is a class of semi-empirical correlations describing the relation between vapor pressure and temperature for pure substances. The Antoine equation is derived from the Clausius–Clapeyron relation. The equation was presented in 1888 by the French engineer Louis Charles Antoine [fr] (1825–1897).
Vapor pressure[a] or equilibrium vapor pressure is the pressure exerted by a vapor in thermodynamic equilibrium with its condensed phases (solid or liquid) at a given temperature in a closed system. The equilibrium vapor pressure is an indication of a liquid's thermodynamic tendency to evaporate. It relates to the balance of particles escaping ...
Trouton's rule. In thermodynamics, Trouton's rule states that the (molar) entropy of vaporization is almost the same value, about 85–88 J/ (K·mol), for various kinds of liquids at their boiling points. [1] The entropy of vaporization is defined as the ratio between the enthalpy of vaporization and the boiling temperature.
The Clausius–Clapeyron relation describes a Phase transition in a closed system composed of two contiguous phases, condensed matter and ideal gas, of a single substance, in mutual thermodynamic equilibrium, at constant temperature and pressure. Therefore, [8]: 508. Using the appropriate Maxwell relation gives [8]: 508 where is the pressure.