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hydrogen sulfide chemosynthesis: [1] 18H 2 S + 6CO 2 + 3 O 2 → C 6 H 12 O 6 (carbohydrate) + 12H 2 O + 18 S. In the above process, hydrogen sulfide serves as a source of electrons for the reaction. [6] Instead of releasing oxygen gas while fixing carbon dioxide as in photosynthesis, hydrogen sulfide chemosynthesis produces solid globules of ...
The free energy created is then used, via a chain of nearby electron acceptors, for a transfer of hydrogen atoms (as protons and electrons) from H 2 O or hydrogen sulfide towards carbon dioxide, eventually producing glucose. These electron transfer steps ultimately result in the conversion of the energy of photons to chemical energy.
The following is a breakdown of the energetics of the photosynthesis process from Photosynthesis by Hall and Rao: [6]. Starting with the solar spectrum falling on a leaf, 47% lost due to photons outside the 400–700 nm active range (chlorophyll uses photons between 400 and 700 nm, extracting the energy of one 700 nm photon from each one)
Venenivibrio stagnispumantis gains energy by oxidizing hydrogen gas.. In biochemistry, chemosynthesis is the biological conversion of one or more carbon-containing molecules (usually carbon dioxide or methane) and nutrients into organic matter using the oxidation of inorganic compounds (e.g., hydrogen gas, hydrogen sulfide) or ferrous ions as a source of energy, rather than sunlight, as in ...
Some bacteria use light energy to couple sulfur oxidation to carbon dioxide (CO 2) fixation for growth. These fall into two general groups: green sulfur bacteria (GSB) and purple sulfur bacteria (PSB). [6] However, some Cyanobacteria are also able to use hydrogen sulfide as an electron donor during anoxygenic photosynthesis. [7]
Economics must reach competitive price to other sources of energy and the economics are dependent on several parameters. A major technical obstacle is the efficiency in converting solar energy into chemical energy stored in molecular hydrogen. Attempts are in progress to solve these problems via bioengineering.
The Gibbs free energy is the energy available ("free") to do work. Any reaction that decreases the overall Gibbs free energy of a system will proceed spontaneously (given that the system is isobaric and also at constant temperature), although the reaction may proceed slowly if it is kinetically inhibited.
The Ukrainian microbiologist Sergei Winogradsky, working in the laboratory of Anton de Bary, showed that these intracellular sulfur globules were formed when Beggiatoa oxidized hydrogen sulfide (H 2 S) as an energy source, with oxygen as the terminal electron acceptor and CO 2 used as a carbon source. [5]