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2 FeCl 3 + Fe → 3 FeCl 2. A traditional synthesis of anhydrous ferrous chloride is the reduction of FeCl 3 with chlorobenzene: [25] 2 FeCl 3 + C 6 H 5 Cl → 2 FeCl 2 + C 6 H 4 Cl 2 + HCl. iron(III) chloride releases chlorine gas when heated above 160 °C, generating ferrous chloride: [16] 2FeCl 3 → 2FeCl 2 + Cl 2
3 + 2 H 2 O ↔ FeOOH + 3 HCl. Therefore, the compound can also be obtained by the decomposition of acidic solutions of iron(III) chloride held near the boiling point for days or weeks: [14] FeCl 3 + 2 H 2 O → FeOOH (s) + 3 HCl (g) (The same process applied to iron(III) nitrate Fe(NO 3) 3 or perchlorate Fe(ClO 4) 3 solutions yields instead ...
Although often abbreviated as Fe 3+, that naked ion does not exist except under extreme conditions. Iron(III) centres are found in many compounds and coordination complexes, where Fe(III) is bonded to several ligands. A molecular ferric complex is the anion ferrioxalate, [Fe(C 2 O 4) 3] 3−, with three bidentate oxalate ions
Although most compounds are referred to by their IUPAC systematic names ... – Fe(ClO 4) 3; Iron(III ... hydroxides, carbonates, acids, or other compounds listed ...
Iron(II) perchlorate is the inorganic compound with the formula Fe(ClO 4) 2 ·6H 2 O. A green, water-soluble solid, it is produced by the reaction of iron metal with dilute perchloric acid followed by evaporation of the solution: [3] Fe + 2 HClO 4 + 6 H 2 O → Fe(ClO 4) 2 ·6H 2 O + H 2
The Cl-O distance in ClO − is 1.69 Å. [2] The name can also refer to esters of hypochlorous acid, namely organic compounds with a ClO– group covalently bound to the rest of the molecule. The principal example is tert-butyl hypochlorite, which is a useful chlorinating agent. [3] Most hypochlorite salts are handled as aqueous solutions.
Chlorate is the common name of the ClO − 3 anion, whose chlorine atom is in the +5 oxidation state.The term can also refer to chemical compounds containing this anion, with chlorates being the salts of chloric acid.
Ba(ClO 3) 2 + H 2 SO 4 → 2 HClO 3 + BaSO 4 The chlorate must be dissolved in boiling water and the acid should be somewhat diluted in water and heated before mixing. Another method which can be used to produce solutions up to 10% concentration is by the use of cation exchange resins and a soluble salt such as NaClO 3 , where the Na+ cation ...