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The electric dipole moment is a measure of the separation of positive and negative electrical charges within a system: that is, a measure of the system's overall polarity. The SI unit for electric dipole moment is the coulomb-metre (C⋅m). The debye (D) is another unit of measurement used in atomic physics and chemistry.
The moment of force, or torque, is a first moment: =, or, more generally, .; Similarly, angular momentum is the 1st moment of momentum: =.Momentum itself is not a moment.; The electric dipole moment is also a 1st moment: = for two opposite point charges or () for a distributed charge with charge density ().
The size of the induced dipole moment is equal to the product of the strength of the external field and the dipole polarizability of ρ. Dipole moment values can be obtained from measurement of the dielectric constant. Some typical gas phase values given with the unit debye are: [7] carbon dioxide: 0; carbon monoxide: 0.112 D; ozone: 0.53 D
Typical dipole moments for simple diatomic molecules are in the range of 0 to 11 D. Molecules with symmetry point groups or containing inversion symmetry will not have a permanent dipole moment, while highly ionic molecular species have a very large dipole moment, e.g. gas-phase potassium bromide, KBr, with a dipole moment of 10.41 D. [3] A proton and an electron 1 Å apart have a dipole ...
Within the Standard Model, such a dipole is predicted to be non-zero but very small, at most 10 −38 e⋅cm, [2] where e stands for the elementary charge. The discovery of a substantially larger electron electric dipole moment would imply a violation of both parity invariance and time reversal invariance. [3] [4]
Class III charges are based on a partitioning of a physical observable derived from the wave function, such as electron density. Class IV charges are derived from a semiempirical mapping of a precursor charge of type II or III to reproduce experimentally determined observables such as dipole moments.
Bond dipole moments are commonly measured in debyes, represented by the symbol D, which is obtained by measuring the charge in units of 10 −10 statcoulomb and the distance d in Angstroms. Based on the conversion factor of 10 −10 statcoulomb being 0.208 units of elementary charge, so 1.0 debye results from an electron and a proton separated ...
The polarizability of an atom or molecule is defined as the ratio of its induced dipole moment to the local electric field; in a crystalline solid, one considers the dipole moment per unit cell. [1] Note that the local electric field seen by a molecule is generally different from the macroscopic electric field that would be measured externally.