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The addition of halogens to alkenes proceeds via intermediate halonium ions. In special cases, such intermediates have been isolated. [5] Bromination is more selective than chlorination because the reaction is less exothermic. Illustrative of the bromination of an alkene is the route to the anesthetic halothane from trichloroethylene: [6]
Classical conditioning occurs when a conditioned stimulus (CS) is paired with an unconditioned stimulus (US). Usually, the conditioned stimulus is a neutral stimulus (e.g., the sound of a tuning fork), the unconditioned stimulus is biologically potent (e.g., the taste of food) and the unconditioned response (UR) to the unconditioned stimulus is an unlearned reflex response (e.g., salivation).
In Kamin's blocking effect [1] the conditioning of an association between two stimuli, a conditioned stimulus (CS) and an unconditioned stimulus (US) is impaired if, during the conditioning process, the CS is presented together with a second CS that has already been associated with the unconditioned stimulus.
Examples of discrimination learning in everyday life can include grocery shopping, determining how to decipher between the types of bread or fruit, being able to tell similar stimuli apart, differentiating between different parts while listening to music, or perhaps deciphering the different notes and chords being played.
Sensory preconditioning is an extension of classical conditioning.Procedurally, sensory preconditioning involves repeated simultaneous presentations (pairing) of two neutral stimuli (NS, e.g. a light and a tone), i.e. stimuli that are not associated with a desired unconditioned response (UR, e.g. salivation).
In Pavlov's original demonstration of classical conditioning, he used a backward conditioning arrangement as the control condition. Briefly, in that procedure, the dogs experienced the same number of US presentations (food) and the same number of CS presentations (metronome ticking) as the experimental groups, but the timing of the CS and US ...
Spontaneous recovery is a phenomenon of learning and memory that was first named and described by Ivan Pavlov in his studies of classical (Pavlovian) conditioning.In that context, it refers to the re-emergence of a previously extinguished conditioned response after a delay. [1]
The halogens (/ ˈ h æ l ə dʒ ə n, ˈ h eɪ-,-l oʊ-,-ˌ dʒ ɛ n / [1] [2] [3]) are a group in the periodic table consisting of six chemically related elements: fluorine (F), chlorine (Cl), bromine (Br), iodine (I), and the radioactive elements astatine (At) and tennessine (Ts), though some authors [4] would exclude tennessine as its chemistry is unknown and is theoretically expected to ...