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The physical properties of the isomers of xylene differ slightly. The melting point ranges from −47.87 °C (−54.17 °F) (m-xylene) to 13.26 °C (55.87 °F) (p-xylene)—as usual, the para isomer's melting point is much higher because it packs more readily in the crystal structure. The boiling point for each isomer is around 140 °C (284 °F).
The m-stands for meta-, indicating that the two methyl groups in m-xylene occupy positions 1 and 3 on a benzene ring. It is in the positions of the two methyl groups, their arene substitution pattern, that it differs from the other isomers, o-xylene and p-xylene. All have the same chemical formula C 6 H 4 (CH 3) 2. All xylene isomers are ...
The p-xylene is then separated out in a series of distillation, adsorption or crystallization and reaction processes from the m-xylene, o-xylene, and ethylbenzene. Its melting point is the highest among this series of isomers, but simple crystallization does not allow easy purification due to the formation of eutectic mixtures.
for m-Xylene/Aniline [7] P = 745 mm Hg BP Temp. °C % by mole m-xylene liquid vapor 167: 10.0: 45.5 160: 19.5: 58.0 153: 34.0: 71.5 146: 53.0: 83.0 143: 71.5: 89.0 ...
In the petroleum refining and petrochemical industries, the initialism BTX refers to mixtures of benzene, toluene, and the three xylene isomers, all of which are aromatic hydrocarbons. The xylene isomers are distinguished by the designations ortho – (or o –), meta – (or m –), and para – (or p –) as indicated in the adjacent diagram.
for p-Xylene/carbon tetrachloride [6] P = 760 mm Hg BP Temp. °C % by mole carbon tetrachloride liquid vapor 136.4: 1.7: 5.9 131.1: 6.3: 21.6 126.2: 11.1: 34.9 121.8 ...
m-xylene (1,3-dimethylbenzene) p-xylene (1,4-dimethylbenzene) Other. Ethylbenzene (not a true xylene but present in mixtures called "mixed xylenes") Styrene;
o-Xylene (ortho-xylene) is an aromatic hydrocarbon with the formula C 6 H 4 (CH 3) 2, with two methyl substituents bonded to adjacent carbon atoms of a benzene ring (the ortho configuration). It is a constitutional isomer of m -xylene and p -xylene , the mixture being called xylene or xylenes.