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In chemistry, a silicic acid (/ s ɪ ˈ l ɪ s ɪ k /) is any chemical compound containing the element silicon attached to oxide (=O) and hydroxyl (−OH) groups, with the general formula [H 2x SiO x+2] n or, equivalently, [SiO x (OH) 4−2x] n. [1] [2] Orthosilicic acid is a representative example.
Orthosilicic acid (/ ˌ ɔːr θ ə s ɪ ˈ l ɪ s ɪ k /) is an inorganic compound with the formula Si(O H) 4. Although rarely observed, it is the key compound of silica and silicates and the precursor to other silicic acids [H 2x SiO x+2] n. Silicic acids play important roles in biomineralization and technology.
Hydrated silica is a form of silicon dioxide, which has a variable amount of water in the formula. When dissolved in water, it is usually known as silicic acid. It is found in nature as opal [2] (which has been mined as a gemstone for centuries), and in the cell walls of diatoms.
Many hydrates and silicic acids exist in the most dilute of aqueous solutions, but these are rather insoluble and quickly precipitate and condense and cross-link to form various polysilicic acids of variable combinations following the formula [SiO x (OH) 4−2x] n, similar to the behaviour of boron, aluminium, and iron, among other elements.
Here, the silicic acid H 4 SiO 4, or Si(OH) 4, which is equivalent to SiO 2 · 2 H 2 O represents hydrous or amorphous silica for the sake of simplicity in aqueous chemistry. Indeed, the term silicic acid has traditionally been used as a synonym for silica, SiO 2. Strictly speaking, silica is the anhydride of orthosilicic acid, Si(OH) 4.
Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula SiO 2, commonly found in nature as quartz. [ 5 ] [ 6 ] In many parts of the world, silica is the major constituent of sand .
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That would have been prepared in 1818 by Johann Nepomuk von Fuchs, by treating silicic acid with an alkali; the result being soluble in water, "but not affected by atmospheric changes". [8] The terms "water glass" and "soluble glass" were used by Leopold Wolff in 1846, [9] by Émile Kopp in 1857, [10] and by Hermann Krätzer in 1887. [11]