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Potassium manganate is the inorganic compound with the formula K 2 MnO 4. This green-colored salt is an intermediate in the industrial synthesis of potassium permanganate (KMnO 4), a common chemical. [1] Occasionally, potassium manganate and potassium permanganate are confused, but each compound's properties are distinct.
The chemical chameleon reaction shows the process in reverse, by reducing violet potassium permanganate first to green potassium manganate and eventually to brown manganese dioxide: [1] [2] [5] KMnO 4 (violet) → K 2 MnO 4 (green) → MnO 2 (brown/yellow suspension) Blue potassium hypomanganate may also form as an intermediate. [6]
For example, addition of potassium permanganate to an aqueous solution of sugar and sodium hydroxide produces the chemical chameleon reaction, which involves dramatic color changes associated with the various oxidation states of manganese. A related vigorous reaction is exploited as a fire starter in survival kits.
A variety of colors, often similar to the colors found in a flame test, are produced in a bead test, which is a qualitative test for determining metals. A platinum loop is moistened and dipped in a fine powder of the substance in question and borax. The loop with the adhered powders is then heated in a flame until it fuses and the color of the ...
A permanganate (/ p ər ˈ m æ ŋ ɡ ə n eɪ t, p ɜːr-/) [1] is a chemical compound with the manganate(VII) ion, MnO − 4, the conjugate base of permanganic acid. Because the manganese atom has a +7 oxidation state, the permanganate(VII) ion is a strong oxidising agent. The ion is a transition metal ion with a tetrahedral structure. [2]
Measurements of pH or colour change are used to derive the equilibrium constant for the reaction. Further hydrolysis may occur, producing dimeric, trimeric or polymeric species containing hydroxy- or oxy- groups. The next step is to determine which model for the chemical processes best fits the experimental data. [citation needed]
Structure of manganate. In inorganic nomenclature, a manganate is any negatively charged molecular entity with manganese as the central atom. [1] However, the name is usually used to refer to the tetraoxidomanganate(2−) anion, MnO 2− 4, also known as manganate(VI) because it contains manganese in the +6 oxidation state. [1]
Potassium permanganate (KMnO 4) is a dark violet colored powder. Its reaction with glycerol (commonly known as glycerin or glycerine) (C 3 H 5 (OH) 3) is highly exothermic, resulting rapidly in a flame, along with the formation of carbon dioxide and water vapour: 14 KMnO 4 (s) + 4 C 3 H 5 (OH) 3 (l) → 7 K 2 CO 3 (s) + 7 Mn 2 O 3 (s) + 5 CO 2 ...